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Synthesis and Study of Composite Materials in the ZrO2(Y2O3)–MgAl2O4 System

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Abstract

Powders–precursors of a tetragonal solid solution based on partially stabilized zirconium dioxide (t-ZrO2) and aluminum-magnesium spinel (MgAl2O4) are synthesized using the method of the cocrystallization of solutions of nitrate salts from which nanocrystalline (<100 nm) composite materials are fabricated at 1400°C in the ZrO2(Y2O3)–MgAl2O4 system with an open porosity of 3%. The structure, physical–mechanical properties, and thermal stability of the nanocomposites are investigated. It is established that the introduction of MgAl2O4 into the matrix of the solid t-ZrO2 solution increases the thermal resistance of the ceramics under the thermal cycling conditions (20–1000°С). The effect of thermal cycling on the phase composition, hardness, and bending strength of the ceramics in the ZrO2(Y2O3)–MgAl2O4 system is investigated.

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    L. V. Morozova, I. A. Drozdova & M. V. Kalinina

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  1. L. V. Morozova
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  2. I. A. Drozdova
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  3. M. V. Kalinina
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Correspondence to L. V. Morozova.

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Translated by D. Marinin

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Morozova, L.V., Drozdova, I.A. & Kalinina, M.V. Synthesis and Study of Composite Materials in the ZrO2(Y2O3)–MgAl2O4 System. Glass Phys Chem 45, 388–394 (2019). https://doi.org/10.1134/S1087659619050092

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  • DOI: https://doi.org/10.1134/S1087659619050092

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