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6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)-1,2- benzoquinone]: Synthesis and properties

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Abstract

Preparation method is developed for a new 6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)- 1,2-benzoquinone], including the stage of 3,5-di(tert-butyl)pyrocatechol aminoalkylation by Mannich reaction followed by oxidation. The molecular structure of one of its hydrolysis products, 4,6-di(tert-butyl)-2,3-dihydroxybenzaldehyde, is established by X-ray diffraction (XRD) analysis.

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Authors and Affiliations

  1. Southern Scientific Center of the Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, 344006, Russia

    Yu. A. Sayapin

  2. Institute of Physical and Organic Chemistry at Southern Federal University, Rostov-on-Don, Russia

    I. O. Tupaeva

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Tkachev & G. V. Shilov

Authors
  1. Yu. A. Sayapin
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  2. I. O. Tupaeva
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  3. V. V. Tkachev
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  4. G. V. Shilov
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Corresponding author

Correspondence to Yu. A. Sayapin.

Additional information

Original Russian Text © Yu.A. Sayapin, I.O. Tupaeva, V.V. Tkachev, G.V. Shilov, 2016, published in Zhurnal Organicheskoi Khimii, 2016, Vol. 52, No. 2, pp. 231–235.

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Sayapin, Y.A., Tupaeva, I.O., Tkachev, V.V. et al. 6,6'-[piperazine-1,4-diylbis(methylene)]bis[3,5-di(tert-butyl)-1,2- benzoquinone]: Synthesis and properties. Russ J Org Chem 52, 214–218 (2016). https://doi.org/10.1134/S1070428016020093

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  • DOI: https://doi.org/10.1134/S1070428016020093

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