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The Synthesis and Investigation of Liquid-Liquid Extraction Capability of N-Diphenylphosphino-N-ethylaniline and Its Chalcogenide Derivatives

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The aminophosphine ligand was synthesized by the reaction of N-ethylaniline with chlorodiphenylphosphine in the presence of triethylamine at low temperature. Oxidation of the ligand with elemental sulfur or selenium afforded the corresponding aminophosphine sulfide and selenide. The compounds were characterized by elemental analyses, IR, 1H and 31P NMR. N-diphenylphosphino-N-ethylaniline and its chalcogen derivatives were used as ligands in solvent extraction of metal picrates such as Cd2+ and Ni2+ from the aqueous to the organic phase. Influences of parameters such as pH of the aqueous phase, solvent, extraction time, and extradant concentration were investigated to determine the extraction ability of ligands for metal ions. Results of the experiments showed that an extractability of 95.5 and 97.8%, respectively for Ni2+, and Cd2+ at pH 2 could be achieved.

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Acknowledgments

This study was supported financially by the Research Projects Unit of Niğde Ömer Halisdemir University with project no. FEB 2015/34.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Niğde Ömer Halisdemir University, Niğde, Turkey

    Y. Akkuşlu & Ö. Sarıöz

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  1. Y. Akkuşlu
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  2. Ö. Sarıöz
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Correspondence to Ö. Sarıöz.

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The authors declare the absence of a conflict of interest that requires disclosure in this article.

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Akkuşlu, Y., Sarıöz, Ö. The Synthesis and Investigation of Liquid-Liquid Extraction Capability of N-Diphenylphosphino-N-ethylaniline and Its Chalcogenide Derivatives. Russ J Appl Chem 92, 817–822 (2019). https://doi.org/10.1134/S1070427219060119

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  • DOI: https://doi.org/10.1134/S1070427219060119

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