Abstract
In this study, we tried to reduce polarization of silica surface by chemically bonding cholorosulfonyl calix[4]arene (CSC[4]A) and silica (Si–O–Cl) to improve dispersion between filler and elastomer. To confirm synthesis of CSC[4]A, 1H NMR, 13C NMR, and IR spectrophotometry were used. Obtained composite of chemically bonded silica and CSC[4]A was characterized by TGA. Compounds (contained silica, silica and silane, silica-calix system) were prepared to investigate the effect of silica-calix system (CSC[4]A-SiO2) on the rheological and mechanical properties of rubber compounds based on natural rubber/cis-butadiene rubber (NR/BR) blend in tire tread formulation. The rheological and mechanical properties of three samples were investigated by different devices and a surface morphology was evaluated by FESEM technique. The results revealed that the curing behavior of the compound with CSC[4]A-SiO2 did not significantly differ from other compounds, while reversion was considerably reduced compared with that to other compounds. Also, the mechanical properties of compound with CSC[4]A-SiO2 were improved dramatically especially in fatigue resistance.
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References
Rodgers, B., Rubber Compounding Chemistry and Application, Akron, Ohio, 2004.
Zhong, B., Jia, Zh., Hu, D., Luo, Y., Jia, D., and Liu, F., Composites: Part A, 2017, vol. 96, pp. 129–136.
Yan, X., Hamed, G.R., and Jia, L., Polym., 2017, vol. 125, pp. 172–181.
Malekzadeh, M., Nouri, H., and Farahani, M., JACR, 2010, vol. 3, pp. 41–45.
Mohapatra, S., Alex, R., and Nando. G.B., J. Appl. Polym. Sci., 2016, vol. 133.
Qiao, H., Chao, M., Hui, D., Liu, J., Zheng, J., Lei, W., Zhou, X., Wang, R., and Zhang, L., Composites Part B, 2017, vol. 114, pp. 356–364.
Xie, Y., Hill, C.A. S., Xiao, Z., Militz, H., and Mai, C., Composites: Part A, 2010, vol. 41, pp. 806–819.
Zhong, B., Jia, Z., Luo, Y., and Jia, D., Composites. Sci. Tech., 2015, vol. 117, pp. 46–53.
Brugnara, A., Topic, F., Rissanen, K., Lande, A., Colassona, B., and Reinauda, O., Chem. Sci., 2014, vol. 5, pp. 3897–3904.
Friebe, S., Gebauer, S., Krauss, G.J., Goermar, G., and Krueger, J., Chromatographic Sci., 1995, vol. 33, pp. 281–284.
Sarma, R.J. and Baruah, J.B., Dyes & Pigments, 2005, vol. 64, pp. 91–92.
Shinkai, S., Tetrahedron, 1993, vol. 49, pp. 8933–8968.
Huang, H., Zhao, C., Ji, Y., Nie, R., Zhou, P., and Zhang, H., J. Hazardous Materials, 2010, vol. 178, pp. 680–685.
Servati, Z., Saber-Tehrani, M., Taghvaei-Ganjali, S., and Zadmard, R., J. Porous Materials, 2018, vol. 25, pp. 1463–1474.
Sliwka-Kaszyńska, M., Jaszczolt, K., Jaszczołt, A., and Rachoń, J., Talanta, 2006, vol. 68, pp. 1560–1566.
Hassan, A.K., Ray, A.K., Nabok, A.V., and Davis, F., Sens. Actuators, 2001, vol. 77, pp. 638–641.
Taghvaei-Ganjali, S., Zadmard, R., Zeyaei, M., Rahnama, K., Faridbod, F., and Ganjali, M.R., Research Letters in Organic Chemistry, 2009, vol. 2009, p. 1.
Hosseini, M., Rahimi, M., Bagheri Sadeghi, H., Taghvaei-Ganjali, S., Dehghan Abkenar, Sh., and Ganjali, M.R., Intern. J. Environ. Anal. Chem., 2015, vol. 89, pp. 407–422.
Mirmoeini, M.S., Alavi Nikje, M.M., Rasouli-Saniabadi, M., and Taghvaei-Ganjali, S., Macromol. Symp., 2017, vol. 373.
Taghvaei-Ganjali, S., Rasouli-Saniabadi, M., and Mirmoeini, M.S., J. Incl. Phenom. Macrocycl. Chem., 2015, vol. 83, pp. 45–52.
Nouri, M., Mozafari, Sh., and Taghvaei Ganjali, S., Iran. JOC., 2011, vol. 3, pp. 807–809.
Li, H., Zhong, Y., Wu, W., Zhang, L., Lai, X., and Zeng. X., J. Appl. Polym. Sci., 2017, vol. 134.
Taghvaei-Ganjali, S., Zadmard, R., and Saber-Tehrani, M., Appl. Surf Sci., 2012, vol. 258, pp. 5925–5932.
Ghosh, P., Katare, S., Patkar, P., Caruthers, J.M., and Venkatasubramanianc, V., Rubber Chem. Technol., 2003, vol. 76, pp. 592–693.
Rabiei, S. and Shojaei, A., Eur. Polym. J, 2016, vol. 81, pp. 98–113.
Boonkerd, K., Deeprasertkul, C., and Boonsomwong, K., Rubber Chem. Technol., 2016, vol. 89, pp. 450–464.
Blok, E.J., Kralevich, M.L., and Varner, J.E., Rubber Chem. Technol., 2000, vol. 73, pp. 114–120.
Nasir, M. and Teh, G.K., Eur. Polym. J., 1988, vol. 24, pp. 733–736.
Polgar, L.M., Fortunato, G., Araya-Hermosilla, R., van Duin, M., Pucci, A., and Picchioni, F., Eur. Polym. J., 2016, vol. 82, pp. 208–219.
Choi, S.S., Kwon, H.M., Kim, Y., Ko, E., and Leeb, K.S., Polym. Int., 2018, vol. 67, pp. 340–346.
Surya, I., Ismail, H., and Azura. A.R., Polym. Test., 2015, vol. 42, pp. 208–214.
Stelescu, M.D., Manaila, E., Craciun, G., Sonmez, M., Georgescu, M., and Nituica, M., Proceedings of the 6th International Conference on Advanced Materials and Systems, Bucharest, Romania, October 20–22, 2016.
Ghosh, P., Stocek, R., Gehde, M., Mukhopadhyay, R., and Krishnakumar, R., Int. J. Fract., 2014, vol. 188, pp. 9–21.
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The authors are grateful to the Research Council of the Islamic Azad University and the Iran Rubber Research Institute for the financial support of this work.
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Mohamadi, H., Motiee, F., Saber Tehrani, M. et al. Preparation and Application of Chemically Bonded Silica Supported Calix[4]arene as Reinforced Filler in NR/BR Blend Based Rubber Compounds. Russ J Appl Chem 92, 809–816 (2019). https://doi.org/10.1134/S1070427219060107
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DOI: https://doi.org/10.1134/S1070427219060107