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Specific features of the interaction of α- and γ-modifications of Al2O3 with carbonate and carbonate-chloride melts

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Data on reactivities of α- and γ-Al2O3 finely dispersed powders in a melted carbonate eutectic (Li2CO3–Na2CO3–K2CO3)eut and carbonate-chloride mixture 0.72(Li2CO3–Na2CO3–K2CO3)eut–0.28NaCl were obtained. The methods of synchronous thermal and X-ray phase analyses and Raman spectroscopy confirmed that, in contrast to γ-Al2O3, α-Al2O3 does not chemically interact with the melted carbonate eutectic and carbonate-chloride mixture (Li2CO3–Na2CO3–K2CO3)eut–NaCl can be recommended as a thickening agent for a carbonate fuel cell.

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References

  1. Remick, R. and Wheeler, D., Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis, Colorado National Renewable Energy Laboratory, 2010.

    Google Scholar 

  2. Kulkarni, A. and Giddey, S., J. Solid State Electrochem., 2012, vol. 16, pp. 3123–3146.

    Article  CAS  Google Scholar 

  3. Broers, G.H.J. and Schenke, M., Hydrocarbon Fuel Cell Technology. New York: Acad. Press, 1965.

    Google Scholar 

  4. Burmakin, E.I., Rodigina, E.N., and Esina, N.O., Tr., Ins. Elektrokhimii, Akad. Nauk SSSR, 1974, pp. 81–84.

    Google Scholar 

  5. Silvera Scaccia, J. Mol. Liquids, 2005, vol. 116, pp. 67–71.

    Article  Google Scholar 

  6. Dronskowski, R., Inorg. Chem., 1993, vol. 32, pp. 1–9.

    Article  CAS  Google Scholar 

  7. Dosmukhamedov, N.K., Kaplan, V.A., Zholdasbai, E.E., and Lyubomirskii, I.A., Mezhdunar. Zh. Prikl. Ffundamental’n. Issled., 2015, no. 9, pp. 255–259.

    Google Scholar 

  8. McPhail, S.J., Leto, L., Della Pietra, M., et al., International Status of Molten Carbonate Fuel Cells Technology, Rome ENEA Relations Central Unit, 2015.

    Google Scholar 

  9. Rexed, I., Pietra, M., McPhail, S., et al., Int. J. Greenhouse Gas Control, 2015, vol. 35, pp. 120–130.

    Article  CAS  Google Scholar 

  10. Locher, C., Meyer, C., and Steinmetz, H., Water Sci. Technol., 2012, vol. 65, pp. 789–794.

    Article  CAS  Google Scholar 

  11. Levin, I. and Brandon, D., J. Am. Ceram. Soc., 1998, vol. 81, pp. 1995–2012.

    Article  CAS  Google Scholar 

  12. Kosenko, N.F., Ogneupory Tekh. Keram., 2010, no. 78, pp. 3–15.

    Google Scholar 

  13. Zakir’yanova, I.D., Arkhipov, P.A., and Zakir’yanov, D.O., J. Appl. Spectrosc., 2016, vol. 82, pp. 920–924.

    Article  Google Scholar 

  14. Janz, G.J. and Lorenz, M.R., J. Chem. Eng. Data, 1961, vol. 6, pp. 321–323.

    Article  CAS  Google Scholar 

  15. Krzhizhanovskii, R.E. and Shtern, Z.Yu., Teplofizicheskie svoistva nemetallicheskikh materialov (Thermal Properties of Nonmetallic Materials), Leningrad Energiya, 1973.

    Google Scholar 

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. Akademicheskaya 20, Yekaterinburg, 620137, Russia

    I. D. Zakir’yanova, I. V. Korzun, V. A. Khokhlov, V. N. Dokutovich, E. V. Nikolaeva & B. D. Antonov

  2. Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Yekaterinburg, 620002, Russia

    I. D. Zakir’yanova, V. A. Khokhlov & E. V. Nikolaeva

Authors
  1. I. D. Zakir’yanova
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  2. I. V. Korzun
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  3. V. A. Khokhlov
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  4. V. N. Dokutovich
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  5. E. V. Nikolaeva
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  6. B. D. Antonov
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Corresponding author

Correspondence to I. D. Zakir’yanova.

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Original Russian Text © I.D. Zakir’yanova, I.V. Korzun, V.A. Khokhlov, V.N. Dokutovich, E.V. Nikolaeva, B.D. Antonov, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 7, pp. 870−876.

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Zakir’yanova, I.D., Korzun, I.V., Khokhlov, V.A. et al. Specific features of the interaction of α- and γ-modifications of Al2O3 with carbonate and carbonate-chloride melts. Russ J Appl Chem 89, 1066–1071 (2016). https://doi.org/10.1134/S1070427216070041

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  • DOI: https://doi.org/10.1134/S1070427216070041

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