Abstract
In this study, saw dust has been used as precursor for production of low cost activated carbon using potassium hydroxide (KOH) and steam activation technique. The activated carbon was used to remove Cs+ and Sr2+ ions from aqueous solutions by batch operation, and the extent of adsorption was investigated as a function of solution pH, temperature, shaking time, and initial concentration. The influence of interfering ions was also investigated. The removal of metal ions was pH dependent and the adsorption capacity reaches its maximum 43% and 61.5% at pH 5.0 and 6.0 for Cs+ and Sr2+ ions, respectively. Thermodynamic studies showed different behaviours where an endothermic, non-spontaneous process was shown for Cs+ while an exothermic, spontaneous process was obtained for Sr2+. The kinetic data of both ions was described well by pseudo-second order rate equation. The two equilibrium models (Langmuir and Freundlich) have been also applied. Desorption studies indicated that HCl was the most effective desorbing eluent. The investigated adsorbent showed good results towards cesium and strontium removal from aqueous media that could be a promising method due to its low-cost and good efficiency.
Similar content being viewed by others
References
Yakout, S.M. and Hassan, H.S., Molecules, 2014, vol. 19, pp. 9160-9172
Abdel Moamena, O.A., Ibrahima, H.A., Abdelmonemb, N., and Ismail, I.M., Micropor. & Mesopor. Mater, 2016, vol. 223, pp. 187–195.
Bruno, R., Duarte, F., Inês, A., João Rocha, P., and Silva, C.M., Chem. Eng. J., 2016, vol. 286, pp. 679–688.
El-Kamash, A.M., J. Hazard. Mater., 2008, vol. 151, pp. 432–445.
Rabiul Awual, Md., Suzuki, S., Taguchi, Y., Shiwaku, H., Okamoto, Y., and Yaita, T., Chem. Eng. J., 2014, vol. 242, pp. 127–135.
Yusan, S. and Erenturk, S., World J. Nuclear Sci. & Techn., 2009, vol. 168, pp. 1070–1081.
Chegrouche, S., Mellah, A., and Barkat, M., Desalination, 2009, vol. 235, pp. 306–318.
Toxicological Profile for Strontium, Agency for Toxic Substances and Disease Registry (ATSDR), 2004.
Lasheen, F., Gad, H.M.H., and El-Zakla, T.S., Radiochem., 2013, vol. 55, no. 6, pp. 589–595.
Lalhmunsiama, C. Lalhriatpui., Diwakar Tiwari, and Seung-Mok Lee, Appl. Sur. Sci., 2014, vol. 321, pp. 275–282.
Bimala Pangeni, Hari Paudyal, Katsutoshi Inoue, Keisuke Ohto, Hidetaka Kawakita, and Shafiq Ala., Chem. Eng. J., 2014, vol. 242, pp. 109–116.
Remenarova, L., Pipiska, M., Florkova, E., Augstin, J., Rozloznik, M., Hostin, S., Hornik, M., Nova Biotech. Chim., 2014, pp. 13–21.
Caccin, M., Giacobbo, F., Da Ros, M., Besozzi, L., and Mariani, M., J. Radioanal. Nucl. Chem., 2013, vol. 297, pp.9–18.
Ahmadpour, A., Zabihi, M., Tahmasbi, M., and Rohani Bastami, T., J. Hazard. Mater., 2010, vol. 182, pp. 552–556.
El-Naggar, I.M., Zakaria, E.S. Ali, I.M., Khalil, M., and El-Shahat, M.F., Arabian J. Chem., 2012, vol. 5, pp.109–119.
Wankasi, D, Horsfall, M. Jn., and Spiff, A.I., African J. Biotechnology, 2005, vol. 4, no. 9, pp. 923–927.
Tae Young Kim, Sang Su An, Wang Geun Shim, Jea Wook Lee, Sung Young Cho, and Jin Hwan Ki., J. Ind. & Eng. Chem., 2015, vol. 27, pp. 260–267.
Saad Ali Kha., Riaz-ur-Rehman, and Ali Khan, M., Waste Manag., 1995, vol. 15, no. 8, pp. 641–650.
Lan Zhang, Jiying Wei, Xuan Zhao, Fuzhi Li, Feng Jiang, Meng Zhang, and Xuzhou Chen., Chem. Eng. J., 2016, vol. 285, pp.679–689.
Nightingale, E.R., Jr., J. Phys. Chem., 1959, vol. 63, pp. 1381–1387
Dahu Ding, Zhongfang Lei, Yingnan Yang, Chuanping Feng, and Zhenya Zhan., J. Hazard. Mater., 2014, vol. 270, pp. 187–195.
Gad, H.M.H. and El-Sayed, A.A., J. Hazard. Mater., 2009, vol. 168, pp. 1070–1081.
Chun-Shui Zhu, Li-Ping Wanga, and Wen-bin Chen., J. Hazard. Mater., 2009, vol. 168, pp. 739–746.
Xunjun Che., Information, 2015, vol. 6, pp. 14–22.
Volchek, K., Miaha, M.Y., Wenxing Kuang, Zack DeMaleki, and Handan Tezel, F., J. Hazard. Mater., 2011, vol. 194, pp. 331–337.
Yakout, S.M., Ph.D. Thesis, Ain Shams University, 2006
Yuh-Shan Ho and Ofomaja, A,E., J. Hazard. Mater., 2006, vol. 129, pp. 137–142.
Saeedeh Hashemian, Hossein Saffari, and Saeedeh Ragabion, Water Air Soil Pollut, 2015, p.226.
Qin Li, Jianping Zhai, Wenyi Zhang, Mingmei Wang, and Jun Zhou, J. Hazard. Mater., 2007, vol, 141, pp. 163–167.
Plazinski, W., Dziuba, J., and Rudzinski, W., Adsorption, 2013, vol. 19, pp.1055–106.
Thermodynamics, Mizutani Tadashi, Ed., 2011.
Prabakaran, R. and Arivoli, S., Int. J. Sci., Eng & Tech. Res., 2013, vol. 2, iss.2.
Blanchard, G., Maunaye, M., and Martin, G., Water Res., 1984, vol. 12, pp. 1501–1507.
Ho, Y.S. and Mckay, G., The Kinetics of Sorption of Basic Dyes from Aqueous Solution by Sphagnum Moss Peat, New York: Wiley, 1998.
Wallace, S.H., Shaw, S., Morris, K., Small, J.S., Fuller, A.J., and Burk, I.T., Appl. Geochem., 2012, vol. 27, pp. 1482–1491
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Gad, H.M.H., Elsanafini, H.A., Ali, M.M.S. et al. Factors affecting the sorption behavior of Cs+ and Sr2+ using biosorbent material. Russ J Appl Chem 89, 988–999 (2016). https://doi.org/10.1134/S1070427216060240
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427216060240