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Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?

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Abstract

Reactions of 1-(chloromethyl)silatrane with organic group 14 element anions [(Me3Si)3E]‒ (E = Si, Ge) generated in situ afforded the corresponding substitution products (Me3Si)3ECH2Si(OCH2CH2)3N, whereas no products of ring-expansion rearrangement were detected. The structure of the isolated compounds was determined by multinuclear NMR spectroscopy.

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Funding

The NMR spectra were recorded under financial support by the Program for the Development of Lomonosov Moscow State University.

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  1. Faculty of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    K. V. Zaitsev & Yu. F. Oprunenko

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  1. K. V. Zaitsev
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Correspondence to K. V. Zaitsev.

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To the 100th Anniversary of M.G. Voronkov

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Zaitsev, K.V., Oprunenko, Y.F. Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?. Russ J Gen Chem 91, 2385–2390 (2021). https://doi.org/10.1134/S1070363221120057

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