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1,1-Dimethyl-1-(trialkoxysilylmethyl)hydrazinium and 1,1-Dimethyl-1-(silatranylmethyl)hydrazinium Halides

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Abstract

Formerly unknown 1,1-dimethyl-1-(trialkoxysilylmethyl)- and 1,1-dimethyl-1-(silatranylmethyl)hydrazinium halides were prepared by reaction of 1,1-dimethylhydrazine with (halomethyl)trialkoxysilanes XCH2Si(OR)3 (X = Cl, I; R=Me, Et) and 1-(halomethyl)silatranes XCH2Si(OCH2CH2)3N (X = Cl, Br). 1,1-Dimethyl-1-(silatranylmethyl)hydrazinium chloride and iodide were also obtained by transetherification of corresponding 1,1-dimethyl-1-(trimethoxysilylmethyl)hydrazinium halides with tris(2-hydroxyethyl)amine.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    M. S. Sorokin & M. G. Voronkov

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  1. M. S. Sorokin
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  2. M. G. Voronkov
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 6, 2005, pp. 915–919.

Original Russian Text Copyright © 2005 by Sorokin, Voronkov.

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Sorokin, M.S., Voronkov, M.G. 1,1-Dimethyl-1-(trialkoxysilylmethyl)hydrazinium and 1,1-Dimethyl-1-(silatranylmethyl)hydrazinium Halides. Russ J Gen Chem 75, 862–866 (2005). https://doi.org/10.1007/s11176-005-0335-6

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  • DOI: https://doi.org/10.1007/s11176-005-0335-6

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