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Synthesis of Novel Tridentate 5-Arylazosalicylaldehyde Thiosemicarbazone Derivatives and Their Complexes with Copper(II)

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Abstract

Herein, novel 5-arylazosalicylaldehyde thiosemicarbazone derivatives (H2L1–12) and their copper(II) complexes have been synthesized and characterized by NMR, IR and UV-Vis spectra and TGA/DTA. The accumulated data exhibit that thiosemicarbazone derivatives bind with copper ion via the deprotonated phenolic-OH, azomethine-N and deprotonated thiol-SH groups. Accordingly, composition of the complexes can be presented as CuL·H2O. The TGA analysis of Cu(II) complexes have revealed their thermal stability up to ca. 170°C.

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Funding

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work under grant number: R.G.P.1/231/41.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, King Khalid University, Mohail, 61421, Assir, Saudi Arabia

    M. A. Salem

  2. Organometallic and Organometalloid Chemistry Department, National Research Centre, 12622, Cairo, Egypt

    S. Y. Abbas & S. A. Darwish

  3. Department of Chemistry, Faculty of Arts and Science, Northern Border University, 76322, Rafha, Saudi Arabia

    M. H. Helal

  4. Chemistry Department, Faculty of Science, Menoufia University, 32511, Menoufia, Egypt

    E. H. Aish

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  1. M. A. Salem
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  2. S. Y. Abbas
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  3. S. A. Darwish
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  4. M. H. Helal
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Corresponding author

Correspondence to S. Y. Abbas.

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Salem, M.A., Abbas, S.Y., Darwish, S.A. et al. Synthesis of Novel Tridentate 5-Arylazosalicylaldehyde Thiosemicarbazone Derivatives and Their Complexes with Copper(II). Russ J Gen Chem 91, 1578–1583 (2021). https://doi.org/10.1134/S1070363221080211

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  • DOI: https://doi.org/10.1134/S1070363221080211

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