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Binuclear copper(II) complexes of 5-nitrosalicylaldehyde N(3)-substituted thiosemicarbazones

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Summary

Binuclear copper(II) complexes with six 5-nitrosalicylaldehyde N(3)-substituted thiosemicarbazones have been prepared and characterized. I.r., electronic and e.s.r. spectra of the complexes, as well as i.r., electronic, and 1H-and 13C-n.m.r. spectra of the thiosemicarbazones, have been obtained. The crystal structure of a monomeric copper(II) complex of 5-nitrosalicylaldehyde piperidyl-thiosemicarbazone, H25NO2Sapip, grown from DMF solution, has been solved. Neither the thiosemicarbazones or their binuclear copper(II) complexes show growth inhibitory activity against Aspergillus niger, but the copper(II) complexes show some activity against the fungus Paecilomyces variotii.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, IL61790, Normal, USA

    Douglas X. West, Michelle M. Salberg, Gordon A. Bain & Anthony E. Liberta

  2. Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, México DF

    Jesús Valdés-Martínez

  3. Ciudad Universitaria, 04510, Coyoacán, México DF

    Simón Hernández-Ortega

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  1. Douglas X. West
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  2. Michelle M. Salberg
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  3. Gordon A. Bain
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  4. Anthony E. Liberta
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  5. Jesús Valdés-Martínez
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  6. Simón Hernández-Ortega
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West, D.X., Salberg, M.M., Bain, G.A. et al. Binuclear copper(II) complexes of 5-nitrosalicylaldehyde N(3)-substituted thiosemicarbazones. Transition Met Chem 21, 206–212 (1996). https://doi.org/10.1007/BF00165968

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  • DOI: https://doi.org/10.1007/BF00165968

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