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Thermo-Oxidative Degradation of Hydroxypolychlorobiphenyls

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Abstract

The degradation of hydroxy derivatives synthesized from individual di-, tri-, tetra-, and pentachlorinated biphenyls as typical representatives of commercial mixtures of polychlorinated biphenyls has been studied by means of synchronous thermal analysis. Exhaustive thermal degradation of the substrate, characterized by the absence of evaporation process and lower energy consumption as compared to thermolysis of technical mixtures of polychlorinated biphenyls as well as the mixtures of their methoxy and hydroxy derivatives, has been established.

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Funding

This study was financially supported by the Russian Foundation for Basic Research (project no. 18-29-24126) and performed using the equipment of the Center for Collective Usage “Spectroscopy and analysis of organic compounds.”

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Authors and Affiliations

  1. I.Ya. Postovskii Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    T. I. Gorbunova & M. G. Pervova

  2. Institute of Metallurgy of the Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    A. V. Maiorova & T. V. Kulikova

  3. Ural Federal University, 620002, Yekaterinburg, Russia

    A. V. Maiorova, T. V. Kulikova & A. P. Safronov

  4. Institute of Electrophysics of the Ural Branch of the Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    A. P. Safronov

Authors
  1. T. I. Gorbunova
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  2. A. V. Maiorova
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  3. T. V. Kulikova
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  4. M. G. Pervova
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  5. A. P. Safronov
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Corresponding author

Correspondence to T. I. Gorbunova.

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No conflict of interest was declared by the authors.

Additional information

Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 8, pp. 1277–1283 https://doi.org/10.31857/S0044460X21080163.

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Gorbunova, T.I., Maiorova, A.V., Kulikova, T.V. et al. Thermo-Oxidative Degradation of Hydroxypolychlorobiphenyls. Russ J Gen Chem 91, 1540–1545 (2021). https://doi.org/10.1134/S1070363221080168

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  • DOI: https://doi.org/10.1134/S1070363221080168

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