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Tris(m-tolyl)antimony Derivatives (3-MeC6H4)3Sb[OC(O)R]2 (R = CH2Cl, C6H3F2-2,3) and [(3-MeC6H4)3SbOSO2C6H3(NO2)2-2,4]2O: Synthesis and Structure

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Abstract

Tris(m-tolyl)antimony dicarboxylates (3-MeC6H4)3Sb[OC(O)CH2Cl]2 and (3-MeC6H4)3Sb[OC(O)C6H3F2-2,3]2 were synthesized by the reaction of tris(m-tolyl)antimony with chloroacetic and 2,3-difluorobenzoic acids in the presence of tert-butyl hydroperoxide (molar ratio 1 : 2 : 1, respectively) in diethyl ether. Under similar conditions, the reaction of tris(m-tolyl)antimony with 2,4-dinitrobenzenesulfonic acid leads to the formation of µ-oxobis-[tris(m-tolyl)(2,4-dinitrobenzenesulfonato)antimony]. The Sb atoms in the resulting compounds have distorted trigonal-bipyramidal coordination with electronegative ligands in axial positions.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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  1. V. V. Sharutin
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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 4, pp. 598–604 https://doi.org/10.31857/S0044460X21040156.

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Sharutin, V.V., Sharutina, O.K. Tris(m-tolyl)antimony Derivatives (3-MeC6H4)3Sb[OC(O)R]2 (R = CH2Cl, C6H3F2-2,3) and [(3-MeC6H4)3SbOSO2C6H3(NO2)2-2,4]2O: Synthesis and Structure. Russ J Gen Chem 91, 672–677 (2021). https://doi.org/10.1134/S1070363221040150

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