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Synthesis of Amido- and Diamidophosphites with Polyfluoroalkyl Substituents

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Abstract

Bis(polyfluoroalkyl) chlorophosphites and polyfluoroalkyl dichlorophosphites react easily with secondary amines (from –40 to –22°C, 1–3 h, CH2Cl2) in the presence or absence of triethylamine to form the corresponding bis(polyfluoroalkyl) diorganylamidophosphites or bis(diorganylamido) polyfluoroalkyl phosphites in the yield of up to 74%. Bis(polyfluoroalkyl) diorganylamidophosphites were also synthesized from diorganylamidodichlorophosphites and polyfluoroalkanols (–25 to –22°C, 2 h, Et3N–CH2Cl2) with a yield of 56–60%.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the Baikal Analytical Center for Collective Use of the Siberian Branch of the Russian Federation.

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Authors and Affiliations

  1. A.E. Favorskii Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033, Irkutsk, Russia

    S. F. Malysheva, N. K. Gusarova, N. A. Belogorlova, N. A. Chernysheva, S. I. Verkhoturova & B. A. Trofimov

  2. Sokol’skii Institute of Fuel, Catalysis, and Electrochemistry, 050010, Almaty, Kazakhstan

    A. M. Nalibayeva & G. K. Bishimbayeva

  3. Irkutsk State University of Communications, 664074, Irkutsk, Russia

    S. V. Yasko

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  1. S. F. Malysheva
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  2. N. K. Gusarova
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  3. N. A. Belogorlova
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  4. A. M. Nalibayeva
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  6. N. A. Chernysheva
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  9. B. A. Trofimov
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Correspondence to B. A. Trofimov.

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Malysheva, S.F., Gusarova, N.K., Belogorlova, N.A. et al. Synthesis of Amido- and Diamidophosphites with Polyfluoroalkyl Substituents. Russ J Gen Chem 90, 229–234 (2020). https://doi.org/10.1134/S1070363220020103

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