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Binding of Gold(III) from Solutions with Thallium(I) Dibutyldithiocarbamate: Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Complex ([Au{S2CN(C4H9)2}2][TlCl4])n

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Abstract

The binding of gold(III) from solution in a 2 M HCl with thallium(I) dibutyl dithiocarbamate leads to the formation of ion-polymeric complex ([Au{S2CN(C4H9)2}2][TlCl4])n, which was studied by (13С, 15N) MAS NMR spectroscopy and X-ray diffraction analysis. In the complex comprising the nonequivalent cations [Au{S2CN(C4H9)2}2]+ (A and B) and anions [TlCl4]–, the supramolecular self-assembly is provided by secondary bonds Au···S and S···Cl. The former are involved in the formation of isomeric binuclear cations [А···А] and [В···В] that build the (···[А···А]···[В···В]···)n polymeric chain; the latter selectively combine the thallium(III) anions and the dimeric cations. Thermolysis of the complex is accompanied by gold recovery and release of TlCl.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far-Eastern Branch, Russian Academy of Sciences, Relochnyi per. 1, Blagoveshchensk, 675000, Russia

    A. V. Ivanov, O. A. Bredyuk & O. V. Loseva

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  1. A. V. Ivanov
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  2. O. A. Bredyuk
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  3. O. V. Loseva
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Correspondence to A. V. Ivanov.

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Original Russian Text © A.V. Ivanov, O.A. Bredyuk, O.V. Loseva, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 7, pp. 1180–1187.

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Ivanov, A.V., Bredyuk, O.A. & Loseva, O.V. Binding of Gold(III) from Solutions with Thallium(I) Dibutyldithiocarbamate: Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Complex ([Au{S2CN(C4H9)2}2][TlCl4])n. Russ J Gen Chem 88, 1470–1477 (2018). https://doi.org/10.1134/S1070363218070198

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