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Synthesis, Supramolecular Self-Organization, and Thermal Behavior of Gold(III)–Thallium(III) Heteronuclear Complexes ([Au{S2CN(CH3)2}2][TlCl4])2 and ([Au{S2CN(C2H5)2}2][TlCl4]) n

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Abstract

The interaction of polymeric thallium(I) dimethyl- and diethyldithiocarbamates with [AuCl4]– in 2 M HCl has been studied. Heteropolynuclear complexes ([Au{S2CN(CH3)2}2][TlCl4])2 (I) and ([Au{S2CN(C2H5)2}2][TlCl4]) n (II) have been preparatively isolated from chemisorption systems [Tl2{S2CNR2}2] n –Au3+/2 M HCl (R = CH3, C2H5). These compounds have been characterized by 13C CP/MAS NMR, and their crystal and supramolecular structures have been determined by X-ray crystallography. Basic structural units of compounds I and II are square-planar [Au{S2CNR2}2]+ cations (with S,S'- bidentate coordination of two Dtc ligands to the gold atom) and distorted tetrahedral [TlCl4]–anions. In supramolecular self-organization, the decisive role is played by relatively weak secondary interactions Au⋯S and Au⋯Cl. With the use of simultaneous thermal analysis, the thermal behavior of I and II have been studied, which enabled the elucidation of temperature-induced transformations and identification of TlCl and reduced gold among the thermolysis products.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Relochnyi per. 1, Blagoveshchensk, 675000, Russia

    A. V. Ivanov, O. A. Bredyuk & O. V. Loseva

  2. Luleå University of Technology, S-971 87, Lulea, Sweden

    O. N. Antzutkin

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  1. A. V. Ivanov
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  2. O. A. Bredyuk
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  3. O. V. Loseva
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  4. O. N. Antzutkin
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Correspondence to A. V. Ivanov.

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Original Russian Text © A.V. Ivanov, O.A. Bredyuk, O.V. Loseva, O.N. Antzutkin, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 6, pp. 792–802.

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Ivanov, A.V., Bredyuk, O.A., Loseva, O.V. et al. Synthesis, Supramolecular Self-Organization, and Thermal Behavior of Gold(III)–Thallium(III) Heteronuclear Complexes ([Au{S2CN(CH3)2}2][TlCl4])2 and ([Au{S2CN(C2H5)2}2][TlCl4]) n . Russ. J. Inorg. Chem. 61, 755–765 (2016). https://doi.org/10.1134/S0036023616060103

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  • DOI: https://doi.org/10.1134/S0036023616060103

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