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Modification of (Poly)Siloxanes via Hydrosilylation Catalyzed by Rhodium Complex in Ionic Liquids

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Summary.

The hydrosilylation of 1-heptene, allyl glycidyl ether and, allyl polyether by heptamethylhydrotrisiloxane and poly(hydro, methyl)(dimethyl)siloxane catalyzed by rhodium(I) complexes (particularly [{Rh(μ–OSiMe 3)(cod)}2]) in imidazolium ionic liquids (especially [TriMIM]MeSO4) gives heptyl and glycidyloxy functional (poly)siloxanes and silicone polyethers with high yield and selectivity. The catalytic system based on rhodium siloxide can be easily separated from the product and successfully reused up to five times.

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Authors and Affiliations

  1. Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland

    Bogdan Marciniec, Hieronim Maciejewski, Karol Szubert & Magdalena Kurdykowska

Authors
  1. Bogdan Marciniec
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  2. Hieronim Maciejewski
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  3. Karol Szubert
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  4. Magdalena Kurdykowska
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Correspondence to Bogdan Marciniec.

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Marciniec, B., Maciejewski, H., Szubert, K. et al. Modification of (Poly)Siloxanes via Hydrosilylation Catalyzed by Rhodium Complex in Ionic Liquids. Monatsh. Chem. 137, 605–611 (2006). https://doi.org/10.1007/s00706-006-0461-9

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  • DOI: https://doi.org/10.1007/s00706-006-0461-9

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