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Phase transitions and thermodynamic properties of lanthanide compounds LnAO4 (A = P, V, Nb)

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

The influence of structural phase transitions, features of electronic structure, and magnetic transformation on the temperature dependence of the heat capacity of LnAO4 (A = P, V, Nb) compounds has been considered. It has been shown that the sum of the contributions to the thermodynamic functions due to the phase transition can vary depending on the lanthanide ion. The contribution to the standard entropy caused by low-temperature phase transitions is the most significant.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    K. S. Gavrichev, M. A. Ryumin, G. E. Nikiforova, K. I. Bryukhanova & A. V. Khoroshilov

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  1. K. S. Gavrichev
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  2. M. A. Ryumin
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  3. G. E. Nikiforova
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  4. K. I. Bryukhanova
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Original Russian Text © K.S. Gavrichev, M.A. Ryumin, G.E. Nikiforova, K.I. Bryukhanova, A.V. Khoroshilov, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, Nos. 1–2, pp. 13–20.

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Gavrichev, K.S., Ryumin, M.A., Nikiforova, G.E. et al. Phase transitions and thermodynamic properties of lanthanide compounds LnAO4 (A = P, V, Nb). Russ J Gen Chem 87, 583–590 (2017). https://doi.org/10.1134/S1070363217030343

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