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Synthesis and Structures of Tri(meta-tolyl)antimony Derivatives (3-MeC6H4)3Sb[OC(O)R]2 (R = CH2C6H4F-3, CH=CHPh, C≡CPh) and [(3-MeC6H4)3SbOSO2CF3]2O

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Abstract

The reactions of tri(meta-tolyl)antimony with 3-fluorophenylchloroacetic, cinnamic, and phenylpropiolic acids in the presence of tert-butyl hydroperoxide (molar ratio 1 : 2 : 1) in diethyl ether afford tri(meta-tolyl)antimony dicarboxylates (3-MeC6H4)3Sb[OC(O)CH2C6H4F-3]2 (I), (3-MeC6H4)3Sb-[OC(O)CH=СHPh]2 (II), and (3-MeC6H4)3Sb[OC(O)C≡СPh]2 (III), respectively. Under similar conditions, the reaction of tri(meta-tolyl)antimony with trifluoromethanesulfonic acid gives µ-oxobis[tri(meta-tolyl)(trifluoromethanesulfonato)antimony] [(3-MeC6H4)3SbOSO2CF3]2O (IV). The Sb atoms in compounds I−IV have the coordination of a distorted trigonal bipyramid with the electronegative ligands in the axial positions.

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  1. South Ural State University (National Research University), 454080, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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Translated by E. Yablonskaya

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Sharutin, V.V., Sharutina, O.K. Synthesis and Structures of Tri(meta-tolyl)antimony Derivatives (3-MeC6H4)3Sb[OC(O)R]2 (R = CH2C6H4F-3, CH=CHPh, C≡CPh) and [(3-MeC6H4)3SbOSO2CF3]2O. Russ J Coord Chem 48, 52–59 (2022). https://doi.org/10.1134/S1070328422010043

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