Abstract
The coordination of meso-tetraphenyltetrabenzoporphyrin and metal exchange of its Cd(II) complex with manganese(II) chloride and acetate in DMF and a chloroform–methanol mixture have been studied by spectrophotometry. The Mn(III) chloride and acetate acido complexes formed in these reactions have been isolated and characterized. The dissolution of the synthesized complexes in DMF in the presence of solid KOH gives Mn(II) meso-tetraphenyltetrabenzoporphyrinate.
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Valentine, J.S. and Quinn, A.E., Inorg. Chem. Commun., 1976, vol. 15, no. 8, p. 1997.
Amerzind, M.J., Hollander, F.J., and Hill, C.L., Inorg. Chem., 1983, vol. 22, no. 25, p. 3776.
Stuzhin, P.A., Repina, N.V., Klyueva, M.E., and Fedotova, E.V., Russ. J. Phys. Chem., 2004, vol. 78, no. 6, p. 864.
Sheinin, V.B., Chizhova, N.V., and Romanova A.O., Russ. J. Gen. Chem., 2010, vol. 80, no. 2, p. 351. doi 10.1134/S107036321002026X.
Chizhova, N.V., Zvezdina, S.V., Kataleva, Yu.S., and Mamardashvili, N.Zh., Russ. J. Gen. Chem., 2015, vol. 85, no. 5, p. 1132. doi 10.1134/S1070363215050217.
Boucher, L.J., Coord. Chem. Rev., 1972, vol. 7, no. 3, p. 289. DOI: 10.1016/S0010-8545(00)80024-7.
Doro, F. G., Lindsay Smith, J. R., Ferreira, A. G., and Assis, M.D., J. Mol. Catal. B, 2000, vol. 164, p. 97. doi 10.1016/S1381-1169(00)00352-6.
Cheng, R.J., Chen, Y.R., and Wang, S.L., Polyhedron, 1993, vol. 12, p. 1353. doi 10.1016/S0277-5387(00) 84326-0.
Kharotonov, S.V., Cand. Sci. (Chem.) Dissertation, Ivanovo, 1982.
Galanin, N.E., Cand. Sci. (Chem.) Dissertation, Ivanovo, 2002
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Original Russian Text © N.V. Chizhova, O.V. Mal’tseva, N.Zh. Mamardashvili, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 8, pp. 1371–1375.
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Chizhova, N.V., Mal’tseva, O.V. & Mamardashvili, N.Z. Synthesis and properties of manganese complexes of meso-tetraphenyltetrabenzoporphyrin. Russ J Gen Chem 86, 1907–1911 (2016). https://doi.org/10.1134/S1070363216080211
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DOI: https://doi.org/10.1134/S1070363216080211