Skip to main content
Log in

Synthesis and properties of manganese complexes of meso-tetraphenyltetrabenzoporphyrin

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The coordination of meso-tetraphenyltetrabenzoporphyrin and metal exchange of its Cd(II) complex with manganese(II) chloride and acetate in DMF and a chloroform–methanol mixture have been studied by spectrophotometry. The Mn(III) chloride and acetate acido complexes formed in these reactions have been isolated and characterized. The dissolution of the synthesized complexes in DMF in the presence of solid KOH gives Mn(II) meso-tetraphenyltetrabenzoporphyrinate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Valentine, J.S. and Quinn, A.E., Inorg. Chem. Commun., 1976, vol. 15, no. 8, p. 1997.

    Article  CAS  Google Scholar 

  2. Amerzind, M.J., Hollander, F.J., and Hill, C.L., Inorg. Chem., 1983, vol. 22, no. 25, p. 3776.

    Article  Google Scholar 

  3. Stuzhin, P.A., Repina, N.V., Klyueva, M.E., and Fedotova, E.V., Russ. J. Phys. Chem., 2004, vol. 78, no. 6, p. 864.

    Google Scholar 

  4. Sheinin, V.B., Chizhova, N.V., and Romanova A.O., Russ. J. Gen. Chem., 2010, vol. 80, no. 2, p. 351. doi 10.1134/S107036321002026X.

    Article  CAS  Google Scholar 

  5. Chizhova, N.V., Zvezdina, S.V., Kataleva, Yu.S., and Mamardashvili, N.Zh., Russ. J. Gen. Chem., 2015, vol. 85, no. 5, p. 1132. doi 10.1134/S1070363215050217.

    Article  CAS  Google Scholar 

  6. Boucher, L.J., Coord. Chem. Rev., 1972, vol. 7, no. 3, p. 289. DOI: 10.1016/S0010-8545(00)80024-7.

    Article  CAS  Google Scholar 

  7. Doro, F. G., Lindsay Smith, J. R., Ferreira, A. G., and Assis, M.D., J. Mol. Catal. B, 2000, vol. 164, p. 97. doi 10.1016/S1381-1169(00)00352-6.

    Article  CAS  Google Scholar 

  8. Cheng, R.J., Chen, Y.R., and Wang, S.L., Polyhedron, 1993, vol. 12, p. 1353. doi 10.1016/S0277-5387(00) 84326-0.

    Article  CAS  Google Scholar 

  9. Kharotonov, S.V., Cand. Sci. (Chem.) Dissertation, Ivanovo, 1982.

    Google Scholar 

  10. Galanin, N.E., Cand. Sci. (Chem.) Dissertation, Ivanovo, 2002

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. V. Chizhova.

Additional information

Original Russian Text © N.V. Chizhova, O.V. Mal’tseva, N.Zh. Mamardashvili, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 8, pp. 1371–1375.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chizhova, N.V., Mal’tseva, O.V. & Mamardashvili, N.Z. Synthesis and properties of manganese complexes of meso-tetraphenyltetrabenzoporphyrin. Russ J Gen Chem 86, 1907–1911 (2016). https://doi.org/10.1134/S1070363216080211

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216080211

Keywords

Navigation