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Synthesis and Structures of Disulfanilamide Glyoxime and Ni(II) and Cu(II) Complexes with This Ligand Stimulating the Proteolytic Properties of [Cu(DsamH2)3]SO4·5H2O

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Abstract

The reaction of dichloroglyoxime with sulfanilamide affords new glyoxime: disulfanilamide glyoxime (DsamH2, L). Two coordination compounds are synthesized from DsamH2: [Ni(DsamH)2]·2H2O (I) and [Cu(DsamH2)3]SO4·5H2O (II). Their compositions and structures are determined by elemental analysis and IR, UV, and NMR spectroscopy. Compounds L and II are studied by XRD (CIF files CCDC nos. 2080777 and 2080778, respectively). Both bis(ligand) and tris(ligand) complexes with L are synthesized depending on the synthesis conditions. The different degrees of deprotonation of the DsamH2 ligand in complexes I and II cause the formation of both molecular and ionic complexes. Complex II taken in optimum concentrations exerts a stimulating effect on the protease synthesis of the biotechnologically significant micromycete strains Fusarium gibbosum CNMN FD 12 and Trichoderma koningii Oudemans CNMN FD 15.

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Funding

This work was carried out in terms of state assignments (projects nos. 20.80009.5007.15 and 20.80009.5007.28) of the National Agency for Research and Development of Republic of Moldova.

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Authors and Affiliations

  1. Institute of Applied Physics, Chisinau, Republic of Moldova

    P. N. Bourosh

  2. Institute of Chemistry, Chisinau, Republic of Moldova

    P. N. Bourosh, A. P. Rija, D. Ureche & I. I. Bulhac

  3. Tiraspol State University, Chisinau, Republic of Moldova

    Ed. B. Coropceanu

  4. Institute of Microbiology and Biotechnology, Chisinau, Republic of Moldova

    A. A. Ciloci, S. F. Clapco, E. G. Dvornina & S. V. Labliuc

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  1. P. N. Bourosh
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  9. I. I. Bulhac
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Translated by E. Yablonskaya

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Bourosh, P.N., Coropceanu, E.B., Rija, A.P. et al. Synthesis and Structures of Disulfanilamide Glyoxime and Ni(II) and Cu(II) Complexes with This Ligand Stimulating the Proteolytic Properties of [Cu(DsamH2)3]SO4·5H2O. Russ J Coord Chem 48, 41–51 (2022). https://doi.org/10.1134/S1070328422010018

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