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Syntheses, Crystal Structures, and Antimicrobial Activities of Copper(II) Complexes Derived from N,N'-Bis(5-Fluorosalicylidene)-1,3-Propanediamine

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Abstract

Two new Schiff base copper(II) complexes, [Cu2L2] (I) and [Cu2L(NCNCN)2]n (II), where L is the dianionic form of N,N'-bis(5-fluorosalicylidene)-1,3-propanediamine (H2L), were synthesized and characterized by elemental analyses, infrared and electronic spectroscopy, and single crystal X-ray determinations (CIF files CCDC. nos. 2000415 (I) and 2000416 (II)). Complex I is a phenolate bridged dinuclear copper(II) compound. Complex II is a phenolate and dicyanoamide bridged polynuclear copper(II) compound. In both complexes, the Cu atoms are in square pyramidal coordination. The Schiff base ligand coordinates to the Cu atoms through the phenolate O and imino N atoms. The Schiff base H2L and the two complexes showed high selectivity and antimicrobial activities against a number of the bacteria and fungi.

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Authors and Affiliations

  1. Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Department of Chemistry, Dezhou University, 253023, Dezhou, P.R. China

    F. M. Wang

  2. School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 100081, Beijing, P.R. China

    L. J. Li, G. W. Zang & T. T. Deng

  3. Department of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, P.R. China

    Z. L. You

Authors
  1. F. M. Wang
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  2. L. J. Li
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  3. G. W. Zang
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  4. T. T. Deng
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  5. Z. L. You
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Correspondence to F. M. Wang.

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Wang, F.M., Li, L.J., Zang, G.W. et al. Syntheses, Crystal Structures, and Antimicrobial Activities of Copper(II) Complexes Derived from N,N'-Bis(5-Fluorosalicylidene)-1,3-Propanediamine. Russ J Coord Chem 47, 225–233 (2021). https://doi.org/10.1134/S1070328421030076

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