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Synthesis, structure, and magnetic properties of magnesium bis-3,6-di-tert-butyl-о-benzosemiquinonate complexes with N-donor ligands

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Abstract

A series of six-coordinate magnesium bis-3,6-di-tert-butyl-о-benzosemiquinonate complexes with different N-donor ligands (2,2´-dipyridyl, 1,10-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, pyridine, N-phenyl-1-(4-pyridinyl)methanimine) were synthesized. The molecular and crystal structures of these complexes were determined by X-ray diffraction. In the complexes with bidentate N-donor ligands, the O,O-diolate o-semiquinone ligands are cis to each other, whereas the compounds with monodentate ligands contain organic radical anions in trans positions. The specific features of magnetic exchange coupling between organic radical ligands were studied by temperature-dependent magnetic susceptibility measurements.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    A. V. Piskunov, A. V. Maleeva & G. K. Fukin

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

Authors
  1. A. V. Piskunov
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  2. A. V. Maleeva
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  3. A. S. Bogomyakov
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  4. G. K. Fukin
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Corresponding author

Correspondence to A. V. Piskunov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences G. A. Abakumov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1618—1628, September, 2017.

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Piskunov, A.V., Maleeva, A.V., Bogomyakov, A.S. et al. Synthesis, structure, and magnetic properties of magnesium bis-3,6-di-tert-butyl-о-benzosemiquinonate complexes with N-donor ligands. Russ Chem Bull 66, 1618–1628 (2017). https://doi.org/10.1007/s11172-017-1933-2

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  • DOI: https://doi.org/10.1007/s11172-017-1933-2

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