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Oxovanadium(IV) Complex with 1-Hydroxyethane-1,1-Diphosphonic Acid and Bis(2-pyridyl-1,2,4-Triazol-3-yl)methane

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Abstract

The synthesis of oxovanadium(IV) complex with 1-hydroxyethane-1,1-diphosphonic acid (H4EDP) anion and bis(2-pyridyl-1,2,4-triazol-3-yl)methane (H2L) is described. The reaction of VOSO4 with H4EDP and H2L followed by neutralization of the reaction mixture with Et3N gives the trinuclear complex [(VO)4(H2L)2(EDP)2(H2O)2]·4H2O (I), which was studied by IR and ESR spectroscopy. The molecular and crystal structures of complex I were determined by X-ray diffraction (CIF file CCDC no. 2022772).

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REFERENCES

  1. Maeda, K., Microporous and Mesoporous Mater., 2004, vol. 73, p. 47.

    Article  CAS  Google Scholar 

  2. Matczak-Jon, E. and Videnova-Adrabinska, V., Coord. Chem. Rev., 2005, vol. 249, p. 2458.

    Article  CAS  Google Scholar 

  3. Fu, R., Hu, S., and Wu, X., Cryst. Growth Des., 2014, vol. 14, p. 6197.

    Article  CAS  Google Scholar 

  4. Mao, J.-G., Coord. Chem. Rev., 2007, vol. 251, p. 1493.

    Article  CAS  Google Scholar 

  5. Bao, S.-S. and Zheng, L.-M., Coord. Chem. Rev., 2016, vol. 319, p. 63.

    Article  CAS  Google Scholar 

  6. Ma Yu-Juan, Hu Ji-Xiang, Han Song-De, et al., J. Am. Chem. Soc., 2020, vol. 142, p. 2682.

    Article  CAS  Google Scholar 

  7. Pan Jie, Ma Yu-Juan, Han Song-De, et al., Cryst. Growth Des., 2019, vol. 19, p. 2919.

    Article  Google Scholar 

  8. Rocha, J., Paz, F.A.A., Shi Fa-Nian, et al., Eur. J. Ino-rg. Chem., 2009, vol. 2009, p. 4931.

    Article  Google Scholar 

  9. Aleksandrov, G.G., Sergienko, V.S., and Afonin, E.G., Cryst. Rep., 2001, vol. 46, no. 1, p. 46.

    Article  Google Scholar 

  10. Ban, R., Liang, Y., Ma, P., et al., Inorg. Chem. Commun., 2016, vol. 71, p. 65.

    Article  CAS  Google Scholar 

  11. Gusev, A.N., Shul’gin, V.F., Ryush, I.O., et al., Eur. J. Inorg. Chem., 2017, p. 704.

  12. Pan Ling-ling, Yuan Yi-xuan, Xiao, Y., et al., J. Mol. Struct., 2008, vol. 892, p. 272.

    Article  CAS  Google Scholar 

  13. SMART (control) and SAINT (integration) Sofware. Version 5.0, Madison: Bruker AXS Inc., 1997.

  14. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  15. Gusev, A.N., Shul’gin, V.F., and Kiskin, M.A., J. Struct. Chem., 2019, vol. 60, no. 3, p. 335.

    Article  CAS  Google Scholar 

  16. Kuska, H.A. and Rogers, M.T., Electron Spin Resonnance of First Row Transition Metal Complex Ions, New York: Interscience, 1968.

    Google Scholar 

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ACKNOWLEDGMENTS

X-ray diffraction analysis was carried out using the research equipment of the resource center of the Science Park “X-ray Diffraction Investigation Methods”, Saint Petersburg State University.

Funding

This study was supported by the Russian Science Foundation (project no. 18-13-00024).

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Authors and Affiliations

  1. Vernadsky Crimean Federal University, Simferopol’, Russia

    V. F. Shul’gin, Yu. I. Baluda & A. N. Gusev

  2. Institute of Chemistry, Saint Petersburg State University, Saint Petersburg, Russia

    M. A. Kryukova

Authors
  1. V. F. Shul’gin
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  2. Yu. I. Baluda
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  3. A. N. Gusev
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  4. M. A. Kryukova
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Corresponding author

Correspondence to V. F. Shul’gin.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Shul’gin, V.F., Baluda, Y.I., Gusev, A.N. et al. Oxovanadium(IV) Complex with 1-Hydroxyethane-1,1-Diphosphonic Acid and Bis(2-pyridyl-1,2,4-Triazol-3-yl)methane. Russ J Coord Chem 47, 204–208 (2021). https://doi.org/10.1134/S1070328421030052

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  • DOI: https://doi.org/10.1134/S1070328421030052

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