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Syntheses, Structural Characterization of Two Cobalt Coordination Polymers Composed of Isophthalate and Bis(4-(1H-imidazol-1-YL)phenyl)methanone Ligands

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Abstract

Two 2D cobalt complexes, namely {[(Bipmo)2Co2(Ipa)2](DMF)]·2.25H2O}n (I), {[(Bipmo)-Co(Ipa)]·2H2O}n (II), have been constructed solvothermally using isophthalic acid (H2Ipa), bis(4-(1H-imidazol-1-yl)phenyl)methanone (Bipmo), and cobalt acetate at different temperatures. Single-crystal X-ray diffraction analyses (CIF files CCDC nos. 2078773 (I), 2078774 (II)) reveal that I and II crystallize in the triclinic and monoclinic systems, space groups \(P\bar {1}\), and P21/c, respectively. Complex I presents a 2D uninodal network with the point symbol {44·62} along [1 1 –1] direction, while complex II shows two fold interpenetration with the same point symbol.

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REFERENCES

  1. Chen, L., Tan, K., Lan, Y.Q., et al., Chem. Commun., 2012, vol. 48, p. 5919.

    Article  CAS  Google Scholar 

  2. Swamy, S.I., Bacsa, J., Jones, J.T.A., et al., J. Am. Chem. Soc., 2010, vol. 132, p. 12773.

    Article  CAS  Google Scholar 

  3. Corma, A., Garcia, H., and Llabres i Xamena, F.X., Chem. Rev., 2010, vol. 110, p. 4606.

    Article  CAS  Google Scholar 

  4. Stylianou, K.C., Warren, J.E., Chong, S.Y., et al., Chem. Commun., 2011, vol. 47, p. 3389.

    Article  CAS  Google Scholar 

  5. Ingram, C.W., Liao, L., Bacsa, J., et al., Cryst. Growth Des., 2013, vol. 13, p. 1131.

    Article  CAS  Google Scholar 

  6. Wang, G.F., Rus. J. Coord. Chem., 2018, vol. 44, p. 540.

    Article  CAS  Google Scholar 

  7. Rao, K.P., Higuchi, M., Duan, J., et al., Cryst. Growth Des., 2013, vol. 13, p. 981.

    Article  CAS  Google Scholar 

  8. Wang, P., Fan, R.-Q., Yang, Y.-L., et al., CrystEngComm, 2013, vol. 15, p. 4489.

    Article  CAS  Google Scholar 

  9. Wang, G.-F., Sun, S.-W., Sun, H., et al., Z. Naturforsch., B, 2020, vol. 75, p. 859.

    Article  CAS  Google Scholar 

  10. Wang, G.-F., Zhang, X., Sun, S.-W., et al., Z. Naturforsch., B, 2017, vol. 72, p. 257.

    Article  CAS  Google Scholar 

  11. Wang, G.-F., Zhang, X., Liu, Z.-R., et al., Z. Naturforsch., B, 2017, vol. 72, p. 83.

    Article  CAS  Google Scholar 

  12. Wang, G.-F., Zhang, X., Sun, S.-W., et al., Z. Naturforsch., B, 2016, vol. 71, p. 869.

    Article  CAS  Google Scholar 

  13. CrysAlis Pro , Version 1.171.35.19, Santa Clara: Agilent Technologies Inc., 2011.

  14. Sheldrick, G.M., SHELXTL-97, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  15. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  16. Hou, X.-Y., Wang, X., Li, S.-N., et al., Cryst. Growth Des., 2017, vol. 17, p. 3229.

    Article  CAS  Google Scholar 

  17. Chen, Z., Gao, D.-L., Diao, C.-H., et al., Cryst. Growth Des., 2012, vol. 12, p. 1201.

    Article  CAS  Google Scholar 

  18. Ugale, B., Dhankhar, S.S., and Nagaraja, C.M., Cryst. Growth Des., 2017, vol. 17, p. 3295.

    Article  CAS  Google Scholar 

  19. Chen, Q., Chang, Z., Song, W.-C., et al., Angew. Chem. Int. Ed., 2013, vol. 52, p. 11550.

    Article  CAS  Google Scholar 

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Funding

This research was supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, P.R. China

    G. F. Wang & S. W. Sun

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  1. G. F. Wang
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  2. S. W. Sun
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Correspondence to G. F. Wang.

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Wang, G.F., Sun, S.W. Syntheses, Structural Characterization of Two Cobalt Coordination Polymers Composed of Isophthalate and Bis(4-(1H-imidazol-1-YL)phenyl)methanone Ligands. Russ J Coord Chem 47, 915–921 (2021). https://doi.org/10.1134/S1070328421120034

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