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Synthesis, spectroscopy and X-ray studies of [N′-(2-hydroxy-3-methoxybenzylidene)-4-methylbenzenesulfonohydrazide]uranyl(IV)

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Abstract

The C30H30N4O10S2U complex (I) has been investigated and characterized by single crystal X-ray diffraction (CIF file CCDC no. 970349), IR and UV-Vis spectroscopic techniques. X-ray results show that the title compound crystallizes in the monoclinic system, space group P21/c with a = 14.8219(14), b = 11.6177(11), c = 20.0854(15) Å, β = 104.268(9)°, V = 3351.9(5) Å3 and Z = 4. In the title structure, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand in the equatorial plane and oxo atoms in the axial positions. The C-S-N(H)-N linkage is non-planar, the torsion angle being −98.7(15)° and the S atom showing a tetrahedral environment. The crystal packing occurs intra-inter molecular N-H⋯O and C-H⋯O hydrogen bonds.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, Kurupelit, Samsun, 55139, Turkey

    N. Şenyüz & H. Batı

  2. Department of Physics, Faculty of Science, Cankiri Karatekin University, Ballica, Cankiri, 18100, Turkey

    Ç. Y. Ataol

Authors
  1. N. Şenyüz
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  2. Ç. Y. Ataol
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  3. H. Batı
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Correspondence to Ç. Y. Ataol.

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Şenyüz, N., Ataol, Ç.Y. & Batı, H. Synthesis, spectroscopy and X-ray studies of [N′-(2-hydroxy-3-methoxybenzylidene)-4-methylbenzenesulfonohydrazide]uranyl(IV). Russ J Coord Chem 40, 849–853 (2014). https://doi.org/10.1134/S1070328414110062

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  • DOI: https://doi.org/10.1134/S1070328414110062

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