Abstract
Compounds [HBipy][Y(NCS)4(Bipy)2] · H2O (I), [HPhen][Y(NCS)4(Phen)2] (II), and [Y(Nic)3(H2O)2]2 (III), where Bipy is 2,2′-bipyridine and Phen is 1,10-phenanthroline, are synthesized and structurally characterized by X-ray diffraction analyses (CIF files CCDC 984621, 984622, and 934971, respectively). In the anionic complexes, the coordination polyhedron of sodium is formed by eight nitrogen atoms, four of which are provided by the acido ligands and four others are given by two molecules of the N-heterocycle. In compounds I and II, the protonated and coordinated diimines together participate in stacking interactions.
Similar content being viewed by others
References
Ilyukhin, A.B. and Petrosyants, S.P., Rus. J. Inorg. Chem., 2012, vol. 57, no. 13, p. 1653.
Petrosyants, S.P., Rus. J. Inorg. Chem., 2013, vol. 58, no. 13, p. 1605.
Zou, J.-P., Luo, S.-L., Li, M.-J., et al., Polyhedron, 2010, vol. 29, no. 13, p. 2674.
Sen, R., Hazra, D.K., Koner, S., et al., Polyhedron, 2010, vol. 29, no. 17, p. 3183.
Ilyukhin, A., Dobrokhotova, Z., Petrosyants, S., and Novotortsev, V., Polyhedron, 2011, vol. 30, no. 16, p. 2654.
APEX II and SAINT, Madison (WI, USA): Bruker AXS Inc., 2007.
Sheldrick, G.M., SADABS, Göttingen (Germany): Univ. of Göttingen, 1997.
Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.
Shpirt, A.M., Ilyukhin, A.B., and Petrosyants, S.P., Rus. J. Coord. Chem., 1999, vol. 25, no. 7, p. 466.
Peterson, E.J., Dreele von, R.B., and Brown, T.M., Inorg. Chem., 1976, vol. 15, no. 2, p. 309.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.P. Petrosyants, A.B. Ilyukhin, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 11, pp. 687–692.
Rights and permissions
About this article
Cite this article
Petrosyants, S.P., Ilyukhin, A.B. Yttrium complexes with N-donor ligands. Russ J Coord Chem 40, 825–830 (2014). https://doi.org/10.1134/S107032841410008X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S107032841410008X