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Development of HLW Partitioning Technologies in Extraction Systems Based on Different Radical Phosphine Oxide in Heavy Diluents at “PA Mayak”

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Radiochemistry Aims and scope

Abstract

“Mayak” production association has convincingly demonstrated the possibility of creating a HLW partitioning scheme based on different radical phosphine oxide in heavy fluorinated or chlorinated diluents, including in the presence of tributyl phosphate. The separation system makes it possible to efficiently recover uranium, plutonium, neptunium, REE–TPE, as well as technetium from solutions (up to 2 M) in HNO3 and separate them into at least two fractions: a fraction of trivalent REE/TPE with the bulk of technetium and a fraction of polyvalent actinides.

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Authors and Affiliations

  1. Federal State Unitary Enterprise Mayak Production Association, 456784, Ozersk, Russia

    M. V. Logunov & Yu. A. Voroshilov

  2. Bochvar High-Technology Scientific Research Institute for Inorganic Materials, 123098, Moscow, Russia

    M. V. Logunov

  3. “Three Arc Mining,” LLC, 198216, St. Petersburg, Russia

    V. A. Babain

Authors
  1. M. V. Logunov
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  2. Yu. A. Voroshilov
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  3. V. A. Babain
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Correspondence to V. A. Babain.

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Translated from Radiokhimiya, No. 5, pp. 438–459, October, 2022 https://doi.org/10.31857/S0033831122050021

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Logunov, M.V., Voroshilov, Y.A. & Babain, V.A. Development of HLW Partitioning Technologies in Extraction Systems Based on Different Radical Phosphine Oxide in Heavy Diluents at “PA Mayak”. Radiochemistry 64, 581–602 (2022). https://doi.org/10.1134/S1066362222050022

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