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Synthesis and crystal-chemical features of two new uranyl chromates with the structures derived from [(UO2)(T6+O4)(H2O) n ]0 (T = Cr6+, S6+, Se6+, n = 0–2)

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Abstract

Two new chromates of hexavalent uranium, [C3H10N][(UO2)(CrO4)(NO3)] (1) and [C2H8N]2[(UO2)2· (CrO4)2(Cr2O7)](H2O)2 (2), were prepared by a combination of hydrothermal synthesis and isothermal evaporation. Compounds 1 and 2 crystallize in the triclinic system, space group \(P\overline 1 \); a = 7.245(3), b = 7.329(3), c = 11.359(4) Å; α = 85.549(6)°, β = 82.547(6)°, γ = 80.174(6)° for 1; a = 7.2063(4), b = 11.5107(7), c = 16.0980(11) Å; α = 70.736(4)°, β = 80.246(4)°, γ = 71.759(4)° for 2. The structures were solved by the direct methods and refined to R 1 = 0.064 [for 1495 reflections with Fo > 4σ(Fo)] and 0.047 [for 4529 reflections with Fo > 4σ(Fo)] for 1 and 2, respectively. The crystal structure of 1 is based on [(UO2)(CrO4)(NO3)]– chains between which the isopropylamine molecules are arranged. In the structure of 2, the amine and H2O molecules are localized between the [(UO2)2(CrO4)2(Cr2O7)]2– layers. The uranyl chromate complexes described are derived from [(UO2)(TO4)(H2O) n ]0 chains (T = Cr6+, S6+, Se6+, n = 0–2). A brief review of uranyl compounds with tetrahedral TO 2–4 anions (T = Cr6+, S6+, Se6+) and similar structural organization is given.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    E. V. Nazarchuk, O. I. Siidra & R. A. Kayukov

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  1. E. V. Nazarchuk
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  2. O. I. Siidra
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  3. R. A. Kayukov
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Correspondence to E. V. Nazarchuk.

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Original Russian Text © E.V. Nazarchuk, O.I. Siidra, R.A. Kayukov, 2016, published in Radiokhimiya, 2016, Vol. 58, No. 6, pp. 490–495.

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Nazarchuk, E.V., Siidra, O.I. & Kayukov, R.A. Synthesis and crystal-chemical features of two new uranyl chromates with the structures derived from [(UO2)(T6+O4)(H2O) n ]0 (T = Cr6+, S6+, Se6+, n = 0–2). Radiochemistry 58, 571–577 (2016). https://doi.org/10.1134/S1066362216060023

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