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Supramolecular templates for the synthesis of new nanostructured uranyl compounds: Crystal structure of [NH3(CH2)9NH3][(UO2)(SeO4)(SeO2OH)](NO3)

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Abstract

Crystals of a new uranyl selenate, [NH3(CH2)9NH3][(UO2)(SeO4)(SeO2OH)](NO3) (1), were prepared by isothermal evaporation from aqueous solution at room temperature. The crystal structure was solved by the direct method \( P\bar 1 \), a = 10.7480(7), b = 13.8847(9), c = 14.6363(10) Å, α = 109.9600(10)°, β = 103.212(2)°, γ = 90.4090(10)°, V = 1990.0(2) Å3, Z= 4) and refined to R 1 = 0.0379 (wR 2 = 0.0636) for 8515 reflections with ¦Fo¦ ≥ 4σF. The structure is based on [(UO2)(SeO4)(SeO2OH)]-layers parallel to the (001) plane. In the structure of 1, there are two crystallographically independent 1,9-diammoniononane cations forming micelles in which the hydrocarbon chains are packed crosswise. The micelles are cylinders with an elliptical cross section and a rough surface. They are organized by the principle of hydrophilic and hydrophobic interactions. The cylinders are separated from each other by layers of triangular NO −3 groups. Compound 1 is an example of organic-inorganic composites with a unidimensional organic substructure in which the protonated chain-like diamine molecules arranged crosswise form cylindrical supramolecular templates.

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Authors and Affiliations

  1. Geological Faculty, St. Petersburg State University, Universitetskaya nab. 7/9, St. Petersburg, 199034, Russia

    V. V. Gurzhiy & S. V. Krivovichev

  2. Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia

    S. V. Krivovichev

  3. University of Notre Dame, Notre Dame, the United States

    P. C. Burns

  4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    I. G. Tananaev & B. F. Myasoedov

Authors
  1. V. V. Gurzhiy
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  2. S. V. Krivovichev
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  3. P. C. Burns
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  4. I. G. Tananaev
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  5. B. F. Myasoedov
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Correspondence to V. V. Gurzhiy.

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Original Russian Text © V.V. Gurzhiy, S.V. Krivovichev, P.C. Burns, I.G. Tananaev, B.F. Myasoedov, 2010, published in Radiokhimiya, 2010, Vol. 52, No. 1, pp. 3–7.

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Gurzhiy, V.V., Krivovichev, S.V., Burns, P.C. et al. Supramolecular templates for the synthesis of new nanostructured uranyl compounds: Crystal structure of [NH3(CH2)9NH3][(UO2)(SeO4)(SeO2OH)](NO3). Radiochemistry 52, 1–6 (2010). https://doi.org/10.1134/S1066362210010017

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  • DOI: https://doi.org/10.1134/S1066362210010017

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