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Pretransition Phenomena Near First-Order Phase Transitions in Ion-Molecular Crystals

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Abstract

Processes of molecular relaxation in Li2SO4, Na2SO4, and K2SO4 sulfates; Li2CO3, Na2CO3, and K2CO3 carbonates; NaClO4 and KClO4 perchlorates; and Ca(NO3)2, Sr(NO3)2, and Ba(NO3)2 nitrates have been investigated by Raman spectroscopy. It is established that the first-order phase transitions in these systems have a stretched character (structural phase transitions in sulfates, carbonates, and perchlorates and crystal–melt phase transitions in nitrates). The existence of a pretransition region is found in all crystals under investigation.

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Authors and Affiliations

  1. Institute of Physics, Federal State Institution of Science Dagestan Scientific Center of Russian Academy of Sciences, Makhachkala, Russia

    A. R. Aliev, I. R. Akhmedov, M. G. Kakagasanov & Z. A. Aliev

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  1. A. R. Aliev
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  2. I. R. Akhmedov
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  3. M. G. Kakagasanov
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  4. Z. A. Aliev
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Translated by A. Sin’kov

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Aliev, A.R., Akhmedov, I.R., Kakagasanov, M.G. et al. Pretransition Phenomena Near First-Order Phase Transitions in Ion-Molecular Crystals. Phys. Solid State 62, 998–1010 (2020). https://doi.org/10.1134/S1063783420060037

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