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Structural Phase Transition Peculiarities in Ion-Molecular Perchlorate Crystals

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Abstract

Molecular relaxation processes are inspected in potassium and cesium perchlorates (KClO4 and CsClO4, respectively) via Raman spectroscopy. A first-order phase transition in KClO4 and CsClO4 crystal perchlorates is found to be extended. A pretransition region is also detected in KClO4 and CsClO4 systems, wherein the vibrational band widths are shown to remain almost unchanged, but abruptly increase at the phase transition point.

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Authors and Affiliations

  1. Amirkhanov Institute of Physics, Dagestan Scientific Center, Russian Academy of Sciences, Makhachkala, Republic of Dagestan, 367025, Russia

    A. R. Aliev, M. M. Gafurov, I. R. Akhmedov, M. G. Kakagasanov & Z. A. Aliev

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  1. A. R. Aliev
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  2. M. M. Gafurov
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  3. I. R. Akhmedov
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  4. M. G. Kakagasanov
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  5. Z. A. Aliev
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Correspondence to A. R. Aliev.

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Original Russian Text © A.R. Aliev, M.M. Gafurov, I.R. Akhmedov, M.G. Kakagasanov, Z.A. Aliev, 2018, published in Fizika Tverdogo Tela, 2018, Vol. 60, No. 6, pp. 1191–1201.

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Aliev, A.R., Gafurov, M.M., Akhmedov, I.R. et al. Structural Phase Transition Peculiarities in Ion-Molecular Perchlorate Crystals. Phys. Solid State 60, 1203–1213 (2018). https://doi.org/10.1134/S1063783418060045

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  • DOI: https://doi.org/10.1134/S1063783418060045

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