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Induced Quasi-Dynamic Disorder in a Structure of Rhenium Ion-Implanted Quartz Glass

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Abstract

The ultraviolet (UV) absorption spectra were studied in UV–Vis–IR quartz glasses exposed to the rhenium ion irradiation at the energy of 30 keV. An increase in ion fluence (5 × 1015–5 × 1017 cm2) is found to result in a characteristic fan-shaped broadening of the optical absorption edge of glasses. The results were interpreted in the context of the generalized Urbach rule (the approximation of ion radiation induced quasi-dynamic disorder). The effective radiation disorder cross section of a glass matrix was evaluated from the dose dependence of characteristic Urbach energy. This parameter was found to vary between 1.07 × 10–17–1.2 × 10–18 cm2 with increasing fluence. The optical gap width of implanted samples was estimated via the Tautz method for allowed direct interband transitions. The relationship between the second-order deformation potential constants, revealing the correlation between the Urbach energy and the optical gap width in a SiO2 quartz glass matrix was established using the equivalence principle of static and dynamic structural disorder.

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FUNDING

This work was supported by the Ministry of Education and Science (State Task no. 3.1485.2017/4.6) and by the Government of the Russian Federation (Statement 211, contract no. 02.A03.21.0006).

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Authors and Affiliations

  1. Ural Federal University Named after the First President of Russia B.N. Yeltsin, Yekaterinburg, Russia

    A. F. Zatsepin, D. Yu. Biryukov, T. V. Shtang & R. A. Parulin

  2. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    N. V. Gavrilov

  3. Department of Physics, Faculty of Science, Al-Azhar University, 71542, Assiut Branch, Egypt

    M. S. I. Koubisy

Authors
  1. A. F. Zatsepin
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  2. D. Yu. Biryukov
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  3. N. V. Gavrilov
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  4. T. V. Shtang
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  5. M. S. I. Koubisy
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  6. R. A. Parulin
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Correspondence to A. F. Zatsepin.

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Translated by O. Maslova

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Zatsepin, A.F., Biryukov, D.Y., Gavrilov, N.V. et al. Induced Quasi-Dynamic Disorder in a Structure of Rhenium Ion-Implanted Quartz Glass. Phys. Solid State 61, 1017–1022 (2019). https://doi.org/10.1134/S1063783419060301

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