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Relaxor ferroelectric properties of the (1–2x)BiScO3 · xPbTiO3 · xPbMg1/3Nb2/3O3 (0.30 ≤ x ≤ 0.46) system

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Abstract

X-ray diffraction, dielectric, piezoelectric, and pyroelectric studies have been performed on ceramic samples of (1–2x)BiScO3 · xPbTiO3 · xPbMg1/3Nb2/3O3 (0.30 ≤ x ≤ 0.46) perovskite-like solid solutions. The solid solution symmetry was found to vary from the rhombohedral (x ≤ 0.38) to tetragonal (x ≥ 0.42) as x increases. The samples with 0.30 < x ≤ 0.42 have properties characteristic of relaxor ferroelectrics, namely the existence of a wide peak in the temperature dependence of the dielectric permittivity at T mε = 390–440 K that shifts to higher temperatures as the frequency increases, narrow unsaturated dielectric hysteresis loops, and an electric field-induced transition to the ferroelectric state at 318 K. The observed features of the dielectric, piezo-, and pyroelectric properties of these solid solutions are explained by the fact that they are relaxor ferroelectrics.

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Authors and Affiliations

  1. Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, Moscow, 119454, Russia

    A. A. Bush, K. E. Kamentsev & M. A. Bekhtin

  2. OAO NII Elpa, Panfilovskii pr. 10, Zelenograd, Moscow, 124460, Russia

    A. G. Segalla

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  1. A. A. Bush
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  2. K. E. Kamentsev
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  3. M. A. Bekhtin
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  4. A. G. Segalla
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Correspondence to A. A. Bush.

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Original Russian Text © A.A. Bush, K.E. Kamentsev, M.A. Bekhtin, A.G. Segalla, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 1, pp. 36–44.

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Bush, A.A., Kamentsev, K.E., Bekhtin, M.A. et al. Relaxor ferroelectric properties of the (1–2x)BiScO3 · xPbTiO3 · xPbMg1/3Nb2/3O3 (0.30 ≤ x ≤ 0.46) system. Phys. Solid State 59, 34–42 (2017). https://doi.org/10.1134/S1063783417010036

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  • DOI: https://doi.org/10.1134/S1063783417010036

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