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Impedance spectroscopy investigation of electrophysical characteristics of the electrode-liquid crystal interface

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Abstract

The behavior of frequency dependences of the impedance of a capacitive measuring cell with a liquid crystal has been investigated in the frequency range from 10−1 to 105 Hz. A method for determining electrophysical characteristics of the liquid crystal in the bulk and at the liquid crystal-metal electrode interface has been proposed and tested for liquid crystals of the alkyl cyanobiphenyl series, which are doped with ionic surfactants. The method is based on the use of an equivalent electrical circuit, which makes it possible to approximate the impedance spectra with the required accuracy, and also on the determination of the frequency at the singular point in the impedance spectra, at which the reactive component of the electric current flowing through the liquid-crystal cell is negligible compared to the active component.

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References

  1. B. A. Belyaev, A. A. Leksikov, A. M. Serzhantov, and V. F. Shabanov, Tech. Phys. Lett. 34(6), 463 (2008).

    Article  ADS  Google Scholar 

  2. V. Ya. Zyryanov, M. N. Krakhalev, O. O. Prishchepa, and A. V. Shabanov, JETP Lett. 86(6), 383 (2007).

    Article  ADS  Google Scholar 

  3. A. L. Alexe-Ionescu, G. Barbero, and I. Lelidis, J. Phys. Chem. B 113, 14747 (2009).

    Article  Google Scholar 

  4. B. A. Belyaev and N. A. Drokin, Phys. Solid State 56(7), 1455 (2014).

    Article  ADS  Google Scholar 

  5. S. Murakami, H. Iga, and H. Naito, J. Appl. Phys. 80(11), 6396 (1996).

    Article  ADS  Google Scholar 

  6. G. Barbero and A. K. Zvezdin, Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 59(2), 1846 (1999).

    Article  Google Scholar 

  7. A.L. Alexe-Ionescu, G. Barbero, and I. Lelidis, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 80, 061203–1 (2009).

    Article  Google Scholar 

  8. M. Mizusaki, T. Miyashita, T. Uchida, Y. Yamada, Y. Ishii, and S. Mizushima, J. Appl. Phys. 102, 014904–1 (2007).

    Article  ADS  Google Scholar 

  9. M. Scalerandi, P. Pagliusi, G. Gipparrone, and G. Barbero, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 69, 051708–1 (2004).

    Article  ADS  Google Scholar 

  10. I. D. Raistrick, Annu. Rev. Mater. Sci. 16, 343 (1986).

    Article  ADS  Google Scholar 

  11. N. G. Bukun and A. E. Ukshe, Russ. J. Electrochem. 45(1), 11 (2009).

    Article  Google Scholar 

  12. A. Serghei, M. Tress, J. R. Sangoro, and F. Kremer, Phys. Rev. B: Condens. Matter 80, 184301–1 (2009).

    Article  ADS  Google Scholar 

  13. Y.-K. Cho and S. Granick, J. Chem. Phys. 119(1), 547 (2003).

    Article  ADS  Google Scholar 

  14. R. J. Klein, S. Zhang, S. Dou, B. H. Jones, R. H. Colby, and J. Runta, Chem. Phys. 124, 144903–1 (2006).

    ADS  Google Scholar 

  15. T. V. Bezrodnaya, V. V. Nesprava, G. A. Puchkovskaya, I. T. Chashechnikova, Yu. P. Boiko, and Ya. Baran, J. Appl. Spectrosc. 78(1), 50 (2011).

    Article  ADS  Google Scholar 

  16. M. G. Tomilin, Interaction of Liquid Crystals with the Surface (Politekhnika, St. Petersburg, 2001) [in Russian].

    Google Scholar 

  17. Yi. Huang, P. J. Bos, and A. Bhowmik, J. Appl. Phys. 108, 064502–1 (2010).

    Article  ADS  Google Scholar 

  18. P. Jasinski, V. Petrovsky, T. Suzuki, and H. U. Anderson, J. Electrochem. Soc. 152(4), J27 (2005).

    Article  Google Scholar 

  19. N. A. Poklonski, N. I. Gorbachuk, S. V. Shpakovski, and A. Wieck, Tech. Phys. 55(10), 1463 (2010).

    Article  Google Scholar 

  20. C. Druon and J. M. Wacrenier, J. Phys. 38, 47 (1977).

    Article  Google Scholar 

  21. A. I. Zhakin, Phys.-Usp. 46(1), 45 (2003).

    Article  ADS  Google Scholar 

  22. P. Patricio, C. R. Leal, L. F. V. Pinto, A. Boto, and M. T. Cidade, Liq. Cryst. 39, 25 (2012).

    Article  Google Scholar 

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Correspondence to B. A. Belyaev.

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Original Russian Text © B.A. Belyaev, N.A. Drokin, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 1, pp. 170–175.

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Belyaev, B.A., Drokin, N.A. Impedance spectroscopy investigation of electrophysical characteristics of the electrode-liquid crystal interface. Phys. Solid State 57, 181–187 (2015). https://doi.org/10.1134/S1063783415010060

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  • DOI: https://doi.org/10.1134/S1063783415010060

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