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Sequence of transformations during ordering of nonstoichiometric compounds with the formation of M 3 X 2-type superstructures

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Abstract

A symmetry analysis of monoclinic, orthorhombic, and trigonal M 3 X 2-type superstructures, which can be formed in highly nonstoichiometric MX y compounds with B1 structure, has been performed. Channels of disorder-order transitions MX y → M 3 X 2 have been determined. It has been shown that two physically allowed sequences of transformations associated with the formation of M 3 X 2 superstructures are possible in nonstoichiometric MX y compounds of Group IV transition metals with decreasing temperature, i.e., “cubic (space group \(Fm\bar 3m\)) disordered MX y phase → orthorhombic (space group Immm) ordered M 3 X 2 phase → orthorhombic (space group C2221) ordered M 3 X 2 phase” and “cubic (space group \(Fm\bar 3m\)) disordered MX y phase → orthorhombic (space group Immm) ordered M 3 X 2 phase → monoclinic (space group C2) ordered M 3 X 2 phase.”

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia

    A. I. Gusev, A. M. Bel’kov, T. D. Vyrodova & A. S. Kurlov

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  1. A. I. Gusev
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  2. A. M. Bel’kov
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  3. T. D. Vyrodova
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  4. A. S. Kurlov
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Correspondence to A. I. Gusev.

Additional information

Original Russian Text © A.I. Gusev, A.M. Bel’kov, T.D. Vyrodova, A.S. Kurlov, 2014, published in Fizika Tverdogo Tela, 2014, Vol. 56, No. 10, pp. 2025–2032.

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Gusev, A.I., Bel’kov, A.M., Vyrodova, T.D. et al. Sequence of transformations during ordering of nonstoichiometric compounds with the formation of M 3 X 2-type superstructures. Phys. Solid State 56, 2092–2099 (2014). https://doi.org/10.1134/S1063783414100151

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