Abstract
A symmetry analysis of monoclinic, orthorhombic, and trigonal M3X2-type superstructures that can be formed in strongly stoichiometric MX y compounds with B1 structure is carried out. Channels of order-disorder transitions MX y → M3X2 are determined. It is shown that, as temperature decreases, two physically admissible sequences of transformations associated with the formation of M3X2 superstructures are possible in nonstoichiometric MX y compounds of group IV transition metals. By an example of vanadium carbide VC y , it is demonstrated that orthorhombic or monoclinic V3C2 superstructures can be obtained with the formation of a nanostructure.
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A. I. Gusev, A. A. Rempel, and A. J. Magerl, Disorder and Order in Strongly Nonstoichiometric Compounds: Transition Metal Carbides, Nitrides, and Oxides (Springer-Verlag, Berlin, 2001).
A. I. Gusev, JETP Lett. 91(3), 119 (2010).
A. I. Gusev and A. A. Rempel, J. Phys. C: Solid State Phys. 20, 5011 (1987).
A. I. Gusev, J. Exp. Theor. Phys. 109(3), 417 (2009).
A. I. Gusev and A. S. Kurlov, in Niobium: Chemical Properties, Applications, and Environmental Effects, Ed. by M. Segers and T. Peeters (Nova Science, New York, 2013), p. 61.
A. S. Kurlov and A. I. Gusev, Phys. Rev. B: Condens. Matter 76, 174115 (2007).
A. S. Kurlov and A. I. Gusev, Tungsten Carbides: Structure, Properties and Application in Hardmetals (Springer-Verlag, Heidelberg, Germany, 2013).
A. S. Kurlov and A. I. Gusev, Physics and Chemistry of Tungsten Carbides (Fizmatlit, Moscow, 2013) [in Russian].
V. Moisy-Maurice, Structure atomique des carbures nonstoechiometriques de metaux de transition. Rapport CEAR-5127 (Commissariat a l’Energie Atomique, Gifsur-Yvette, France, 1981).
V. Moisy-Maurice, C. H. de Novion, A. N. Christensen, and W. Just, Solid State Commun. 39, 661 (1981).
V. N. Lipatnikov, A. Kottar, L. V. Zueva, and A. I. Gusev, Phys. Solid State 40(7), 1211 (1998).
C. H. de Novion, B. Beuneu, T. Priem, N. Lorenzelli, and A. Finel, in The Physics and Chemistry of Carbides, Nitrides, and Borides, Ed. by R. Freer (Kluwer, Dordrecht, The Netherlands, 1990), p. 329.
V. N. Lipatnikov, A. A. Rempel, and A. I. Gusev, Int. J. Refract. Met. Hard Mater. 16, 61 (1997).
A. I. Gusev and A. A. Rempel, J. Phys. Chem. Solids 55, 299 (1994).
W. Lengauer, Acta Metall. Mater. 39, 2985 (1991).
A. I. Gusev and A. A. Rempel’, Dokl. Akad. Nauk 332, 717 (1993).
A. A. Rempel’ and A. I. Gusev, JETP Lett. 69, 472 (1999).
A. I. Gusev and A. A. Rempel, in Nanostructures: Synthesis, Functional Properties and Applications (ed. by T. Tsakalakos, I. A. Ovid’ko, and A. K. Vasudevan), NATO Science Series II: Mathematics, Physics and Chemistry, vol. 12. (Kluwer Acad. Publ., Dordrecht, 2003), p. 313.
A. I. Gusev, Nonstoichiometry, Disorder, Short-Range and Long-Range Order in the Solid State (Fizmatlit, Moscow, 2007) [in Russian].
A. I. Gusev, Phys.—Usp. 43(1), 1 (2000).
A. I. Gusev, J. Phys. Chem. 74, 510 (2000).
O. V. Kovalev, Irreducible and Induced Representations and Co-Representations of Fedorov’s Groups (Nauka, Moscow, 1986) [in Russian].
A. I. Gusev and A. A. Rempel, Phys. Status Solidi A 135, 15 (1993).
A. S. Kurlov and A. I. Gusev, Phys. Solid State 52(2), 370 (2010).
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Original Russian Text © A.I. Gusev, 2015, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2015, Vol. 147, No. 1, pp. 105–111.
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Gusev, A.I. A sequence of transformations related to the formation of M3X2-type superstructures. J. Exp. Theor. Phys. 120, 91–96 (2015). https://doi.org/10.1134/S1063776115010112
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DOI: https://doi.org/10.1134/S1063776115010112