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Mn(II) and Zn(II) Complexes Constructed by Bis(4-(1H-Imidazol-1-yl)phenyl)methanone and Salicylate: Syntheses and Crystal Structures

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Abstract

Two complexes with V-shaped ligands, [(L1)2Mn(H2O)4](HSA)2] (1), {[(L1)2Zn(H2O)2](HSA)2}n (2) (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2SA = salicylic acid), have been synthesized under solvothermal conditions. The complexes have been characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction analysis. Crystals of 1 and 2 are both triclinic with space group P\(\overline 1 \). In 1, adjacent molecules [(L1)2Mn(H2O)4](HSA)2] are linked by weak interactions to form a 3D network. In 2, Zn2+ ions are linked to each other through the L1 ligands to form 1D infinite chains, which are linked by weak interactions to form a 3D network.

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ACKNOWLEDGMENTS

This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), the Applied Research Projects of Yuncheng University (CY-2018019), and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000 P. R., Yuncheng, China

    G.-F. Wang, S.-W. Sun & W.-J. Bao

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  1. G.-F. Wang
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  2. S.-W. Sun
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  3. W.-J. Bao
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Correspondence to G.-F. Wang or W.-J. Bao.

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Wang, GF., Sun, SW. & Bao, WJ. Mn(II) and Zn(II) Complexes Constructed by Bis(4-(1H-Imidazol-1-yl)phenyl)methanone and Salicylate: Syntheses and Crystal Structures. Crystallogr. Rep. 66, 1247–1252 (2021). https://doi.org/10.1134/S1063774521070191

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  • DOI: https://doi.org/10.1134/S1063774521070191

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