Abstract
Two complexes [Mn(H2O)4(L1)2](bz)2 (1) and {[Zn(L1)(bz)2]}n (2) (L1 = bis(4-(1H-imidazol-1-yl)phenyl) methanone, Hbz = benzoic acid) are synthesized under solvothermal conditions. They are characterized by IR, elemental, and single crystal X-ray diffraction analyses. The single crystal X-ray diffraction analysis shows that Mn1 in 1 has a distorted octahedral geometry with four O atoms from H2O and two N atoms from two L1 ligands, while Zn1 in 2 is four coordinated by two O atoms from two bz2– ligands and two N atoms from two L1 ligands, forming 1D helix chains along the a axis.
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Funding
We are grateful for financial support from the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), Applied Research Projects of Yuncheng University (CY-2018019) and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857), special programs of excellent Ph. D. working in Shanxi Province (QZX-2020003).
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Wang, G.F., Sun, S.W., Sun, H. et al. TWO COMPLEXES ASSEMBLED FROM BIS(4-(1H-IMIDAZOL-1-YL)PHENYL)METHANONE AND BENZOIC ACID: SYNTHESES AND STRUCTURAL CHARACTERIZATION. J Struct Chem 62, 111–115 (2021). https://doi.org/10.1134/S0022476621010133
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DOI: https://doi.org/10.1134/S0022476621010133