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Research Progress on the Solid Electrolyte of Solid-State Sodium-Ion Batteries

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Abstract

Because sodium-ion batteries are relatively inexpensive, they have gained significant traction as large-scale energy storage devices instead of lithium-ion batteries in recent years. However, sodium-ion batteries have a lower energy density than lithium-ion batteries because sodium-ion batteries have not been as well developed as lithium-ion batteries. Solid-state batteries using solid electrolytes have a higher energy density than liquid batteries in regard to applications with sodium-ion batteries, making them more suitable for energy storage systems than liquid batteries. Due to their low ionic conductivity, solid electrolytes are currently unable to achieve comparable performance to liquid electrolytes at room temperature. In this review, we discuss the advancements in SSEs applied to sodium-ion batteries in recent years, including inorganic solid electrolytes, such as Na–β-Al2O3, NASICON and Na3PS4, polymer solid electrolytes based on PEO, PVDF-HFP and PAN, and plastic crystal solid electrolytes mainly composed of succinonitrile. Additionally, appropriate solutions for low ionic conductivity, a narrow electrochemical stability window and poor contact with electrodes, which are the significant flaws in current SSEs, are discussed in this review.

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Acknowledgements

This work was supported by the Natural Science Foundation of China (22005190, 21938005), the Science & Technology Commission of Shanghai Municipality (20QB1405700, 19DZ1205500), and the Zhejiang Key Research and Development Program (2020C01128).

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Authors and Affiliations

  1. Shanghai Electrochemical Energy Devices Research Center, Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Shuzhi Zhao, Xiao-Zhen Liao & Zi-Feng Ma

  2. Zhejiang Natrium Energy Co., Ltd., Shaoxing, 312300, Zhejiang, China

    Haiying Che, Haixiang Tao & Jianping Liao

  3. School of Chemical and Materials Engineering, Jiangnan University, Wuxi, 214122, Jiangsu, China

    Suli Chen

  4. Shaoxing Research Institute of Renewable Energy and Molecular Engineering Shanghai Jiao Tong University, Shaoxing, 312300, Zhejiang, China

    Zi-Feng Ma

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  1. Shuzhi Zhao
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  4. Haixiang Tao
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Correspondence to Haiying Che or Zi-Feng Ma.

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Zhao, S., Che, H., Chen, S. et al. Research Progress on the Solid Electrolyte of Solid-State Sodium-Ion Batteries. Electrochem. Energy Rev. 7, 3 (2024). https://doi.org/10.1007/s41918-023-00196-4

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