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Growth of Crystals of Solid Solutions with Tysonite Structure in the PbF2–RF3 Systems (R = Pr, Nd)

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Abstract

Crystals of the R1 – yPbyF3 – y (R = Pr (0 ≤ y ≤ 0.09) or Nd (0 ≤ y ≤ 0.10)) solid solutions with a tysonite structure (sp. gr. \(P\bar {3}c1\)) have been grown for the first time by the vertical directional melt crystallization in a fluorinating atmosphere using a special crucible for maintaining overpressure. The experimental data have been used to calculate the concentration dependences of the lattice parameters of the R1 – yPbyF3 – y (R = Pr, Nd) solid solutions.

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Funding

This study was supported by the Russian Foundation for Basic Research (projects nos. 17-00-00118 and 19-02-00877) in the part concerning the improvement of the technique for growing crystal and by the Ministry of Science and Higher Education of the Russian Federation within a State assignment in the part concerning the characterization of crystals using the equipment of the Shared Research Center of the FSRC “Crystallography and Photonics” RAS (project RFMEFI62119X0035).

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

    I. I. Buchinskaya, N. A. Arkharova, A. G. Ivanova & D. N. Karimov

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  1. I. I. Buchinskaya
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  2. N. A. Arkharova
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  3. A. G. Ivanova
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  4. D. N. Karimov
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Corresponding author

Correspondence to I. I. Buchinskaya.

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Translated by E. Bondareva

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Buchinskaya, I.I., Arkharova, N.A., Ivanova, A.G. et al. Growth of Crystals of Solid Solutions with Tysonite Structure in the PbF2–RF3 Systems (R = Pr, Nd). Crystallogr. Rep. 65, 147–151 (2020). https://doi.org/10.1134/S106377452001006X

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  • DOI: https://doi.org/10.1134/S106377452001006X

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