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Synthesis and crystal structure of (CN3H6)2[UO2(OH)2(NCS)]NO3 and β-Cs3[UO2(NCS)5]

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Abstract

Compounds (CN3H6)2[UO2(OH)2(NCS)]NO3 (I) and β-Cs3[UO2(NCS)5] (II) are synthesized and studied by IR spectroscopy and single-crystal X-ray diffraction. I and II crystallize in the orthorhombic system. For I, a = 12.2015(13) Å, b = 7.3295(8) Å, c = 16.310(2) Å, space group Pnma, Z = 4, and R = 0.0327; for II, a = 21.7891(6) Å, b = 13.5120(3) Å, c = 6.8522(2) Å, space group Pnma, Z = 4, and R = 0.0268. In structure I, complex groups form infinite chains [UO2(OH)2(NCS)] n− n belonging to the AM 22 M 1 crystal chemical group of uranyl complexes (A = UO 2+2 , M 2 = OH−, and M 1 = NCS−). The main structural elements of crystals II are mononuclear [UO2(NCS)5]3− groups belonging to the AM 15 group of uranyl complexes (A = UO 2+2 and M 1 = NCS−). In I and II, uranium-containing complexes are connected with outer-sphere cations by electrostatic interactions, and in I a system of hydrogen bonds also contributes to their binding. Specific features of the packing of complex [UO2(NCS)5]3− groups in the structures of two modifications of Cs3[UO2(NCS)5] are discussed.

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Authors and Affiliations

  1. Samara State University, ul. Akademika Pavlova 1, Samara, 443011, Russia

    V. N. Serezhkin, M. O. Karasev & L. B. Serezhkina

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

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  1. V. N. Serezhkin
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  2. E. V. Peresypkina
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  3. M. O. Karasev
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  4. A. V. Virovets
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  5. L. B. Serezhkina
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Correspondence to L. B. Serezhkina.

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Original Russian Text © V.N. Serezhkin, E.V. Peresypkina, M.O. Karasev, A.V. Virovets, L.B. Serezhkina, 2014, published in Kristallografiya, 2014, Vol. 59, No. 2, pp. 242–247.

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Serezhkin, V.N., Peresypkina, E.V., Karasev, M.O. et al. Synthesis and crystal structure of (CN3H6)2[UO2(OH)2(NCS)]NO3 and β-Cs3[UO2(NCS)5]. Crystallogr. Rep. 59, 196–201 (2014). https://doi.org/10.1134/S1063774514020199

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  • DOI: https://doi.org/10.1134/S1063774514020199

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