Abstract
Aqueous micro-emulsions of dibutyl dixantogen as an active compound of commercial flotation agent are produced and analyzed using the methods of dynamic light scattering and zeta potential measurements. It is found that the typical hydrodynamic diameter of dixantogen drops is of the order of 300 nm and their zeta potentials are negative. The effect exerted on properties of hydrophobic (pyrolytic graphite) and hydrophilic (silicon dioxide) surfaces by pretreatment with micro-emulsions is examined using the atomic-force microscopy method and colloid probe (SiO2 micro-sphere). The long-range highamplitude attraction forces, probably of capillary nature, are revealed between the probe and substrata after the contact with dixantogen for 1 min. It is supposed that these forces are conditioned by the action of gas nano-structures (nano-bubbles, nano-cavities, etc.) initiated on the surface rendered hydrophobic by dixantogen.
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References
Abramov, A.A., Flotatsionnye metody obogashcheniya (Mineral Flotation Processes), Moscow: Gornaya Kniga, 2008.
Buckley, A.N., Hope, G.A., and Woods, R., Metals from Sulfide Minerals: The Role of Adsorption of Organic Reagents in Processing Technologies, K. Wandelt, S. Thurgate (Eds.), Topics in Applied Physics, vol. 85, Solid–Liquid Interfaces: Macroscopic Phenomena—Microscopic Understanding, Berlin: Springer-Verlag, 2000, vol. 85.
Kartio, I., Laajalehto, K., Suoninen, E., Karthe, S., and Szargan, R., Technique for XPS Measurements of Volatile Adsorbed Layers: Application to Studies of Sulfide Flotation, Surf. Interface Anal., 1992, vol. 18.
Zhang, Y., Cao, Z., Cao, Y., and Sun, C., FTIR Studies of Xanthate Adsorption on Chalcopyrite, Pentlandite and Pyrite Surfaces, J. Mol. Struct., 2013, vol. 1048.
Vigdergauz, V.E. and Kondrat’ev, S.A., Role of Dixantogen in Froth Flotation, J. Min. Sci., 2009, vol. 45, no. 4, pp. 398–403.
Mikhlin, Y.L., Karacharov, A.A., and Likhatskii, M.N., Effect of Adsorption of Butyl Xanthate on Galena, PbS, and HOPG Surfaces as Studied by Atomic Force Microscopy and Spectroscopy and XPS, Int. J. Miner. Proc., In press. DOI:10.1016/j.minpro, 2015, vol. 144.
Juncal, L.C., Tobón, Y.A., Piro, O.E., Della Védova, C.O., and Romano, R.M., Structural, Spectroscopic and Theoretical Studies on Dixantogens: (ROC(S)S)2, with R = n-propyl and isopropyl, New. J. Chem., 2014, vol. 38.
Thormann, E., Simonsen, A.C., Hansen, P.L., and Mouritsen, O.G., Interactions between a Polystyrene Particle and Hydrophilic and Hydrophobic Surfaces in Aqueous Solutions, Langmuir, 2000, vol. 24.
Hampton, M.A. and Nguyen, A.V., Nano-Bubbles and the Nanobubble Bridging Capillary Force, Adv. Colloid Interf. Sci., 2010, vol. 154.
Troncoso, P., Saavedra, J.H., Acuña, S.M., Jeldres, R., Concha F., and Toledo P.G., Nanoscale Adhesive Forces between Silica Surfaces in Aqueous Solutions, J. Colloid Interf. Sci., 2014, vol. 424.
Walczyk, W. and Schönherr, H., Dimensions and the Profile of Surface Nanobubbles: Tip-Nanobubble Interactions and Nanobubble Deformation in Atomic Force Microscopy, Langmuir, 2014, vol. 30.
Tabor, R.F., Grieser, F., Dagastine, R.R., and Chan, D.Y.C., The Hydrophobic Force: Measurements and Methods, Phys. Chem. Chem. Phys., 2014, vol. 16.
Lu, Y.-H., Yang, C.-W., Fang, C.-K., Ko, H.-C., and Hwan, I.-S. Interface-Induced Ordering of Gas Molecules Confined in a Small Space, Sci. Rep., 2014, vol. 4. 7189; DOI:10.1038/srep07189.
Yang, J., Duan, J., Fornasiero, D., and Ralston, J., Very Small Bubble Formation at the Solid–Water Interface, J. Phys. Chem. B., 2003, vol. 107.
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Primary Russian Text © A.A. Karacharov, M.N. Likhatskii, Yu.L. Mikhlin, 2016, published in Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, 2016, No. 1, pp. 178–183.
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Karacharov, A.A., Likhatskii, M.N. & Mikhlin, Y.L. Water emulsions of dibutyl dixantogen and their interaction with the surface of highly oriented pyrolytic graphite and silicon dioxide. J Min Sci 52, 184–189 (2016). https://doi.org/10.1134/S1062739116010285
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DOI: https://doi.org/10.1134/S1062739116010285