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Emulsion Synthesis and Electrophoretic Concentration of Gold Nanoparticles in Sodium Bis(2-Ethylhexyl) Sulfosuccinate Solution in n-Decane

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Abstract

Organosols of gold nanoparticles are obtained by hydrazine reduction of a chloroauric acid solution in a dynamic emulsion of water in n-decane stabilized with a surfactant, sodium bis(2-ethylhexyl) sulfosuccinate. The gold nanoparticles are characterized by phase analysis light scattering, photon correlation spectroscopy, transmission and scanning electron microscopy, X-ray phase analysis, spectrophotometry, thermal analysis, and elemental analyses. The hydrodynamic diameter (≈8 nm), electrophoretic mobility (3.9 × 10–10 m2/(V s)), and electrokinetic potential (30 mV) of the synthesized particles are determined. A liquid-phase concentrate of nanoparticles is separated from the organosol by nonaqueous electrophoresis. Hydrophobic electrically conducting films with a contact angle of 115° and a specific resistance of 0.41 Ω/mm2 are obtained by the thermal treatment of the concentrate.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    N. O. Shaparenko, A. T. Arymbaeva, M. G. Demidova, P. E. Plyusnin, A. N. Kolodin, E. A. Maksimovskii, I. V. Korol’kov & A. I. Bulavchenko

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    P. E. Plyusnin, A. N. Kolodin, E. A. Maksimovskii, I. V. Korol’kov & A. I. Bulavchenko

Authors
  1. N. O. Shaparenko
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  2. A. T. Arymbaeva
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  3. M. G. Demidova
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  4. P. E. Plyusnin
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  5. A. N. Kolodin
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  6. E. A. Maksimovskii
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  7. I. V. Korol’kov
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  8. A. I. Bulavchenko
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Correspondence to N. O. Shaparenko.

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Translated by E. Khozina

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Shaparenko, N.O., Arymbaeva, A.T., Demidova, M.G. et al. Emulsion Synthesis and Electrophoretic Concentration of Gold Nanoparticles in Sodium Bis(2-Ethylhexyl) Sulfosuccinate Solution in n-Decane. Colloid J 81, 478–486 (2019). https://doi.org/10.1134/S1061933X1904015X

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  • DOI: https://doi.org/10.1134/S1061933X1904015X

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