Skip to main content
SpringerLink
Log in

Novel Adsorbents for the Determination of Amino Acids in Soil Extracts by Hydrophilic Interaction Liquid Chromatography with Mass Spectrometric Detection

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Adsorbents based on various substrates—silica and a copolymer of styrene with divinylbenzene—are developed for the determination of amino acids by hydrophilic interaction liquid chromatography—mass spectrometry. The optimal version of the structure of the functional layer in two series of the obtained stationary phases was chosen, which provides the best hydrophilization for each substrate. Retention mechanisms were studied and the conditions for the mass-spectrometric detection, separation, and determination of 16 amino acids were chosen. The applicability of the obtained adsorbents and a method for determining amino acids for the analysis of soil extracts were estimated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Dell’mour, M., Jaitz, L., Oburger, E., Puschenreiter, M., Koellensperger, G., and Hann, S., J. Sep. Sci., 2010, vol. 33, p. 911.

    Article  PubMed  Google Scholar 

  2. Weiss, J., Handbook of Ion Chromatography, Weinheim: Wiley, 2016, 4th ed.

    Book  Google Scholar 

  3. Themelis, T., Gotti, R., and Gatti, R., J. Pharm. Biomed. Anal., 2017, vol. 145, p. 751.

    Article  CAS  PubMed  Google Scholar 

  4. Qiu, J., Craven, C., Wawryk, N., Carroll, K., and Li, X., J. Environ. Sci., 2022, vol. 117, p. 190.

    Article  CAS  Google Scholar 

  5. Violi, J.P., Bishop, D.P., Padula, M.P., Westerhausen, M.T., and Rodgers, K.J., J. Chromatogr. A, 2021, vol. 1655, p. 462530.

    Article  CAS  PubMed  Google Scholar 

  6. Kaczynski, P. and Iwaniuk, P., J. Food Compost. Anal., 2021, vol. 98, p. 103837.

    Article  Google Scholar 

  7. Kohler, I., Derks, R.J.E., and Giera, M., LC GC Eur., 2016, vol. 29, p. 60.

    Google Scholar 

  8. Schriewer, A., Heilen, K.J., Hayen, H., and Jiang, W., Appl. Notebook, 2017, vol. 30, p. 386.

    Google Scholar 

  9. Thermo Scientific Application note 73151: Underivatized amino acid analysis in wine by HILIC separation and mass detection. https://assets.thermofisher.com/ TFS-Assets/CMD/Application-Notes/an-73151-hilic-ms-amino-acids-wine-an73151-en.pdf. Accessed December 7, 2022.

  10. Agilent Application note: Methods for the Analysis of Underivatized Amino Acids by LC/MS. http://www.agilent.com/cs/library/applications/5991-8582EN_HILIC_Underivatized_Amino_Acid_application.pdf. Accessed December 7, 2022.

  11. Uzhel, A.S., Gorbovskaya, A.V., Zatirakha, A.V., Smolenkov, A.D., and Shpigun, O.A., J. Chromatogr. A, 2018, vol. 1589, p. 65.

    Article  PubMed  Google Scholar 

  12. Uzhel, A.S., Gorbovskaya, A.V., Zatirakha, A.V., Smolenkov, A.D., and Shpigun, O.A., J. Chromatogr. A, 2019, vol. 1596, p. 117. https://doi.org/10.1016/j.chroma.2019.03.006

    Article  CAS  PubMed  Google Scholar 

  13. Uzhel, A.S., Zatirakha, A.V., Smolenkov, A.D., and Shpigun, O.A., J. Chromatogr. A, 2019, vol. 1602, p. 310. https://doi.org/10.1016/j.chroma.2019.05.052

    Article  CAS  PubMed  Google Scholar 

  14. Uzhel, A.S., Gorbovskaya, A.V., Zatirakha, A.V., Smolenkov, A.D., and Shpigun, O.A., J. Chromatogr. A, 2020, vol. 1634, p. 461648. https://doi.org/10.1016/j.chroma.2020.461648

    Article  CAS  PubMed  Google Scholar 

  15. Baygildiev, T., Zatirakha, A., Rodin, I., Braun, A., Stavrianidi, A., Koryagina, N., Rybalchenko, I., and Shpigun, O., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2017, vol. 1058, p. 32.

    Article  CAS  Google Scholar 

  16. Liu, J., Wang, Y., Cheng, H., Wang, N., Wu, S., Zhang, P., and Zhu, Y., Talanta, 2016, vol. 159, p. 272.

    Article  CAS  PubMed  Google Scholar 

  17. Shchukina, O.I., Zatirakha, A.V., Smolenkov, A.D., Nesterenko, P.N., and Shpigun, O.A., J. Chromatogr. A, 2015, vol. 1408, p. 78.

    Article  CAS  PubMed  Google Scholar 

  18. Zhang, K., Lou, C., Zhu, Y., Zhi, M., Zeng, X., and Shou, D., Talanta, 2019, vol. 194, p. 485.

    Article  CAS  PubMed  Google Scholar 

  19. Chikurova, N.Yu., Shemiakina, A.O., Shpigun, O.A., and Chernobrovkina, A.V., J. Chromatogr. A, 2022, vol. 1666, p. 462804.

    Article  CAS  PubMed  Google Scholar 

  20. Chikurova, N.Yu., Shemyakina, A.O., Bryskina, D.E., Nuriev, V.N., Komarov, A.A., Statkus, M.A., Stavrianidi, A.N., and Chernobrovkina, A.V., J. Anal. Chem., 2021, vol. 76, p. 1083.

    Article  CAS  Google Scholar 

  21. Domling, A. and Ugi, I., Angew. Chem., 2000, vol. 39, p. 3168.

    Article  CAS  Google Scholar 

  22. Zatirakha, A.V., Smolenkov, A.D., Pirogov, A.V., Nesterenko, P.N., and Shpigun, O.A., J. Chromatogr. A, 2014, vol. 1323, p. 104.

    Article  CAS  PubMed  Google Scholar 

  23. Jin, G., Guo, Z., Zhang, F., Xue, X., Jin, Y., and Liang, X., Talanta, 2008, vol. 76, p. 522.

    Article  CAS  PubMed  Google Scholar 

  24. Kawachi, Y., Ikegami, T., Takubo, H., Ikegami, Y., Miyamoto, M., and Tanaka, N., J. Chromatogr. A, 2011, vol. 1218, p. 5903.

    Article  CAS  PubMed  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation, project no. 20 13 00140, using the equipment of the Central Collective Use Center of Moscow State University “Technologies for Obtaining New Nanostructured Materials and Their Comprehensive Study”, acquired by Moscow State University under the program for updating the instrumentation base within the framework of the national project “Science” and within the framework of the Development Program of Moscow State University.

Author information

Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    N. Yu. Chikurova, A. V. Gorbovskaia, A. N. Stavrianidi, A. O. Shemyakina, A. S. Uzhel, A. V. Chernobrovkina & O. A. Shpigun

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. N. Stavrianidi, E. S. Fedorova & A. K. Buryak

Authors
  1. N. Yu. Chikurova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Gorbovskaia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Stavrianidi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. S. Fedorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. O. Shemyakina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. K. Buryak
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. S. Uzhel
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. V. Chernobrovkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. O. A. Shpigun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Chernobrovkina.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Kudrinskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chikurova, N.Y., Gorbovskaia, A.V., Stavrianidi, A.N. et al. Novel Adsorbents for the Determination of Amino Acids in Soil Extracts by Hydrophilic Interaction Liquid Chromatography with Mass Spectrometric Detection. J Anal Chem 78, 922–932 (2023). https://doi.org/10.1134/S1061934823070043

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934823070043

Keywords:

Search

Navigation