Abstract
It is believed that information about the molecular structure of highly toxic O-alkyl-S-2(N,N-dialkylamino) ethyl alkylthiophosphonates (V-gases) obtained from their EI mass spectra is too insufficient. In particular, the determination of molecular weights and structures of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Aleksandrov, V.N. and Emel’yanov, V.I., Otravlyayushchie veshchestva (Chemical Warfare Agents), Sokol’skii, G.A., Ed., Moscow: Voennoe Izd., 1990.
Gupta, R.C., Veterinary Toxicology: Basic and Clinical Principles, New York: Academic, 2007.
U.S. chemical weapons stockpile and destruction sites map and photos. http://publicintelligence.net/uschem-weapons/. Cited May 13, 2015.
Ellison, D.H., Handbook of Chemical and Biological Warfare Agents, CRC Press, 2007.
GE 92-61926: Convention on the Prohibiting Development, Production, Stockpiling, and Use of Chemical Weapons and on Their Destruction, Paris, 1993.
Recommended Operating Procedures for Analysis in the Verification of Chemical Disarmament, Vanninen, P., Ed., Helsinki: VERIFIN, Univ. Helsinki, 2011.
Morozik, Yu.I., Kuchinskii, E.V., Galyaev, G.V., and Smirnov, A.O., J. Anal. Chem., 2013, vol. 68, no. 8, p. 680.
Kireev, A.F., Rybal’chenko, I.V., Savchuk, V.I., Suvorkin, V.N., Tipukhov, V.N., and Khamidi, B.A., J. Anal. Chem., 2002, vol. 57, no. 8, p. 708.
Kireev, A.F., Rybal’chenko, I.V., Savchuk, V.I., Suvorkin, V.N., and Kholstov, V.I., J. Anal. Chem., 2000, vol. 55, no. 9, p. 837.
NIST Mass Spectral Search Program for the NIST/EPA/NIH Mass Spectral Library (NIST 05), NIST, June 2005.
OPCW Central Analytical Database, e-OCAD, Ver. 16, Technical Secretariat of the Organization for the Prohibition of Chemical Weapons, 2014.
Terent’ev, A.G., Khatymov, R.V., and Ivanova, M.V., Proceedings of the RAS Ufa Scientific Centre, 2014, no. 3, p. 86.
Ioffe, B.V. and Zenkevich, I.G., Dokl. Akad. Nauk SSSR, 1982, vol. 262, no. 5, p. 1150.
Ioffe, B.V., Russ. J. Org. Chem., 1996, vol. 32, no. 5, p. 623.
Zenkevich, I.G. and Ioffe, B.V., Interpretatsiya massspektrov organicheskikh soedinenii (Interpretation of the Mass Spectra of Organic Compounds), Ioffe, B.V., Ed., Leningrad: Khimiya, 1986.
Vul’fson, N.S., Zaikin, V.G., and Mikaya, A.I., Massspektrometriya organicheskikh soedinenii (Mass Spectrometry of Organic Compounds), Moscow: Khimiya, 1986.
Silverstein, R.M., Bassler, G.C., and Morrill, T.C., Spectrometric Identification of Organic Compounds, New York: Wiley, 1991.
Lebedev, A.T., Mass-spektrometriya v organicheskoi khimii (Mass Spectrometry in Organic Chemistry), Moscow: Binom, 2003.
Takhistov, V.V., Organicheskaya mass-spektrometriya (Organic Mass Spectrometry), Leningrad: Nauka, 1990.
Lebedev, A.T., Morozik, Yu.I., Myasoedov, B.F., Rybal’chenko, I.V., and Fomenko, P.V., Mass-Spektrometriya, 2007, vol. 4, no. 4, p. 255.
Smirnov, A.O., Morozik, Yu.I., and Fomenko, P.V., Russ. J. Gen. Chem., 2009, vol. 79, no. 2, p. 203.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.G. Terentyev, Yu.I. Morozik, I.V. Rybal’chenko, A.V. Dudkin, A.O. Smirnov, G.V. Galyaev, 2015, published in Mass-spektrometriya, 2015, Vol. 12, No. 4, pp. 259–267.
Rights and permissions
About this article
Cite this article
Terentyev, A.G., Morozik, Y.I., Rybal’chenko, I.V. et al. Determination of the structural features of O-alkyl-S-2-(N,N-dialkylamino) ethyl alkylthiophosphonates from their electron ionization mass spectra. J Anal Chem 71, 1266–1274 (2016). https://doi.org/10.1134/S1061934816130104
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934816130104