Abstract
Macroporous viscoelastic poly(vinyl alcohol) (PVA) cryogels are formed via the cryogenic processing (freezing/incubation in the frozen state/defrosting) of concentrated solutions of the polymer. Such materials are of significant scientific and applied interest. This also concerns various complex and composite PVA cryogels containing soluble and insoluble (fillers) additives, respectively. Novel organo-inorganic hybrid PVA cryogels containing silica components have been obtained and studied in this work. These hybrid cryogels are formed via the interaction of sodium silicate with hydrochloric acid, which are introduced into an aqueous PVA solution immediately before its cryogenic processing. As a result, the transformation of the inorganic components occurs simultaneously with the cryotropic gelation of PVA. It has been found that the physicomechanical properties, heat endurance, and macroporous morphology of the obtained samples depend on the concentration of the inorganic additives and the temperature conditions of the cryogenic process. Moreover, it has been revealed that formed NaCl and additionally polarized hydrogen bonds between OH groups of PVA and silanol groups of in situ formed poly/oligo(silicic acids) have substantial effects on the characteristics of resulting hybrid cryogels.
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REFERENCES
Kudaibergenov, S.E., Ibraeva, Zh.E., Yashkarova, M.G., and Bekturov, E.A., Kompozitsionnye gidrogelevye materialy (Composite Hydrogel Materials), Semei: Izd. Gos. Univ. im. Shakarima, 2011.
Lozinskii, V.I., Usp. Khim., 1998, vol. 67, p. 641.
Nambu, M., Kobunshi Ronbunshu, 1990, vol. 47, p. 695.
Lazzeri, L., Trends Polym. Sci., 1996, vol. 4, p. 249.
Chu, K.C. and Rutt, B.K., Magn. Reson. Med., 1997, vol. 37, p. 314.
Hassan, C.M. and Peppas, N.A., Adv. Polym. Sci., 2000, vol. 153, p. 37.
Surry, K.J.M., Austin, H.J.B., Fenster, A., and Peters, T.M., Phys. Med. Biol., 2004, vol. 49, p. 5529.
Hoskins, P.R., Ultrasound Med. Biol., 2008, vol. 34, p. 693.
Jagur-Grodzinski, J., Polym. Adv. Technol., 2010, vol. 21, p. 21.
Alves, M.H., Jensen, B.E.B., Smith, A.A.A., and Zelikin, A.N., Macromol. Biosci., 2011, vol. 11, p. 1293.
Baker, M.I., Walsh, S.P., Schwatz, Z., and Boyan, B.D., J. Biomed. Mater. Res. B, 2012, vol. 100, p. 1451.
Iatridis, J.C., Nicoll, S.B., Michalek, A.J., Walter, B.A., and Gupta, M.S., Spine J., 2013, vol. 13, p. 243.
Wan, W., Bannerman, A.D., Yang, L., and Mak, H., Adv. Polym. Sci., 2014, vol. 263, p. 283.
Kumar, A. and Han, S.S., Int. J. Polym. Mater. Polym. Biomater., 2017, vol. 66, p. 159.
Timofejeva, A., D’Este, M., and Loca, D., Eur. Polym. J., 2017, vol. 95, p. 547.
Teodorescu, M., Bercea, M., and Morariu, S., Polym. Rev., 2018, vol. 58, p. 247.
Lozinskii, V.I., Vakula, A.S., and Zubov, A.L., Biotekhnologiya, 1992, no. 4, p. 5.
Varfolomeev, S.D., Rainina, E.I., and Lozinsky, V.I., Pure Appl. Chem., 1992, vol. 64, p. 1193.
Lozinsky, V.I. and Plieva, F.M., Enzyme Microb. Technol., 1998, vol. 23, p. 227.
Lozinsky, V.I., Plieva, F.M., Galaev, I.Y., and Mattiasson, B., Bioseparation, 2001, vol. 10, p. 163.
Lozinskii, V.I., Usp. Khim., 2002, vol. 71, p. 559.
Lozinsky, V.I., Galaev, I.Y., Plieva, F.M., Savina, I.N., Jungvid, H., and Mattiasson, B., Trends Biotech., 2003, vol. 21, p. 445.
Plieva, F.M., Galaev, I.Y., Noppe, W., and Mattiasson, B., Trends Microbiol., 2008, vol. 16, p. 543.
Lozinskii, V.I., Izv. Ross. Akad. Nauk, Ser. Khim., 2008, no. 5, p. 996.
Mattiasson, B., Adv. Polym. Sci., 2014, vol. 263, p. 245.
Efremenko, E.N., Lyagin, I.V., and Lozinsky, V.I., in Supermacroporous Cryogels: Biomedical and Biotechnological Applications, Kumar, A., Ed., Boca Raton, FL: CRC Press, Taylor & Francis Group, LLC, 2016, p. 301.
Gutiérrez, M.C., Aranaz, I., Ferrer, M.L., and del Monte, F., in Macroporous Polymers: Production, Properties and Biotechnological/Biomedical Applications, Mattiasson, B., Kumar, A., and Galaev, I.Y., Eds., Boca Raton, FL: CRC Press, 2010, p. 83.
Gun'ko, V.M., Savina, I.N., and Mikhalovsky, S.V., Adv. Colloid Interface Sci., 2013, vols. 187–188, p. 1.
Iijima, M., Kosaka, S., Hatakeyama, T., and Hatakeyama, H., J. Therm. Anal. Calorim., 2016, vol. 123, p. 1809.
Stejskal, J. and Bober, P., Colloid Polym. Sci., 2018, vol. 296, p. 989.
Gupta, T., Pradhan, A., Bandyopadhyay-Ghosh, S., and Ghosh, S.B., Polym. Adv. Technol., 2019, vol. 30, p. 2392.
Altunina, L.K., Kuvshinov, V.A., and Dolgikh, S.N., in Advances in Geological Storage of Carbon Dioxide, Lombardi, S., Altunina, L.K., and Beaubien, S.E., Eds., Heidelberg: Springer, 2006, p. 103.
Altunina, L.K., Fufaeva, M.S., Filatov, D.A., Svarovskaya, L.I., Rozhdestvenskii, E.A., and Gan-Erdene, E., Eurasian Soil Sci., 2014, vol. 47, p. 425.
Vasiliev, N.K., Ivanov, A.A., Sokurov, V.V., Shatalina, I.N., and Vasilyev, K.N., Cold Reg. Sci. Technol., 2012, vol. 70, p. 94.
Vasiliev, N.K., Pronk, A.D.C., Shatalina, I.N., Janssen, F.H.M.E., and Houben, R.W.G., Cold Reg. Sci. Technol., 2015, vol. 115, p. 56.
Lozinsky, V.I., Podorozhko, E.A., Nikitina, Ya.B., Klabukova, L.F., Vasil’ev, V.G., Burmistrov, A.A., Kondrashov, Yu.G., and Vasiliev, N.K., Colloid J., 2017, vol. 79, p. 497.
Glushkov, D.O., Kuznetsov, G.V., Nigay, A.G., Yanovsky, V.A., and Yashitina, O.S., Power Technol., 2020, vol. 360, p. 65.
Peppas, N.A. and Stauffer, S.R., J. Control. Release, 1991, vol. 16, p. 305.
Lozinsky, V.I., Adv. Polym. Sci., 2014, vol. 263, p. 1.
Suzuki, A. and Sasaki, S., J. Eng. Med., 2015, vol. 229, p. 828.
Lozinsky, V.I., Gels, 2018, vol. 4. https://doi.org/10.3390/gels4030077
Lozinsky, V.I., Vainerman, E.S., Domotenko, L.V., Mamtsis, A.M., Titova, E.F., Belavtseva, E.M., and Rogozhin, S.V., Colloid Polym. Sci., 1986, vol. 264, p. 19.
Watase, M. and Nishinari, K., Makromol. Chem., 1989, vol. 190, p. 155.
Nishinari, K., Watase, M., and Tanaka, F., J. Chim. Phys. (Paris), 1996, vol. 93, p. 880.
Lozinsky, V.I., Damshkaln, L.G., Shaskol’skii, B.L., Babushkina, T.A., Kurochkin, I.N., and Kurochkin, I.I., Colloid J., 2007, vol. 69, p. 747.
Lozinsky, V.I., Damshkaln, L.G., Kurochkin, I.N., and Kurochkin, I.I., Colloid J., 2008, vol. 70, p. 189.
Lozinsky, V.I. and Okay, O., Adv. Polym. Sci., 2014, vol. 263, p. 49.
Podorozhko, E.A., Ul’yabaeva, G.R., Tikhonov, V.E., Kil’deeva, N.R., and Lozinsky, V.I., Colloid J., 2020, vol. 82, p. 36.
Lozinsky, V.I., Zubov, A.L., and Titova, E.I., Enzyme Microb. Technol., 1997, vol. 20, p. 182.
Lozinskii, V.I. and Savina, I.N., Colloid J., 2002, vol. 64, p. 336.
Zhou, H., Shi, T., and Zhou, X., J. Biomater. Sci.-Polym. E, 2014, vol. 25, p. 641.
Lozinsky, V.I., Bakeeva, I.V., Presnyak, E.P., Damshkaln, L.G., and Zubov, V.P., J. Appl. Polym. Sci., 2007, vol. 105, p. 2689.
Luo, X., Akram, M.Y., Yuan, Y., Nie, J., and Zhu, X., J. Appl. Polym. Sci., 2018, vol. 135.
Pomogailo, A.D., Usp. Khim., 2000, vol. 69, p. 60.
Hench, L.L. and West, J.K., Chem. Rev., 1990, vol. 90, p. 33.
Lozinsky, V.I., Sakhno, N.G., Damshkaln, L.G., Bakeeva, I.V., Zubov, V.P., Kurochkin, I.N., and Kurochkin, I.I., Colloid J., 2011, vol. 73, p. 243.
Iler, R.K., The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry, New York: Wiley-Interscience, 1979.
Lipatov, Y.S., Adv. Polym. Sci., 1977, vol. 22, p. 1.
Pan, Y., Wang, J., and Pan, C., Micro Nano Lett., 2012, vol. 7, p. 880.
Gonzalez, J.S. and Alvarez, V.A., J. Mech. Behav. Biomed. Mater., 2014, vol. 34, p. 47.
Zhang, C., Wang, J., Chi, R., Shi, J., Yang, Y., and Zhang, X., Mater. Des., 2019, vol. 183. Article 108166.
Hrouz, J., Ilavsky, M., Havliček, J., and Dušek, K., Collect. Czech. Chem. Commun., 1978, vol. 43, p. 1999.
Guenet, J.M., Thermoreversible Gelation of Polymers and Biopolymers, London: Acad. Press, 1992.
Eldridge, J.E. and Ferry, J.D., J. Phys. Chem., 1954, vol. 58, p. 992.
Hatakeyama, T., Yamauchi, A., and Hatakeyama, H., Eur. Polym. J., 1987, vol. 23, p. 361.
Hassan, C.M. and Peppas, N.A., Macromolecules, 2000, vol. 33, p. 2472.
Auriemma, F., De Rosa, C., and Triolo, R., Macromolecules, 2006, vol. 39, p. 9429.
Domotenko, L.V., Lozinskii, V.I., Vainerman, E.S., and Rogozhin, S.V., Vysokomol. Soedin., Ser. A, 1988, vol. 30, p. 1661.
Hatakeyema, T., Uno, J., Yamada, C., Kishi, A., and Hatakeyama, H., Thermochim. Acta, 2005, vol. 431, p. 144.
Lozinsky, V.I., Domotenko, L.V., Zubov, A.L., and Simenel, I.A., J. Appl. Polym. Sci., 1996, vol. 61, p. 1991.
Dai, L.X., Ukai, K., Shaheen, S.M., and Yamaura, K., Polym. Int., 2002, vol. 51, p. 715.
Shaheen, S.M., Ukai, K., Dai, L.X., and Yamaura, K., Polym. Int., 2002, vol. 51, p. 1390.
Shaheen, S.M. and Yamaura, K., Polym. Adv. Technol., 2003, vol. 14, p. 686.
Patachia, S., Florea, C., Freidrich, C., and Tho-mann, Y., eXPESS Polym. Lett., 2009, vol. 3, p. 320.
Gusev, D.G., Lozinsky, V.I., Vainerman, E.S., and Bakhmutov, V.I., Magn. Res. Chem., 1990, vol. 28, p. 651.
Mikhalev, O.I., Serpinski, M., Lozinsky, V.I., Kapanin, P.V., Chkheidze, I.I., and Alfimov, M.V., Cryo-Lett., 1991, vol. 12, p. 197.
De Rosa, C., Auriemma, F., and Di Girolamo, R., Adv. Polym. Sci., 2014, vol. 263, p. 159.
Sergeev, G.B. and Batyuk, V.A., Usp. Khim., 1976, vol. 45, p. 793.
Watase, M., Nihon Kagaku Kaisi, 1983, no. 9, p. 1254.
Remy, H., Lehrbuch der Anorganischen Chemie, Akad. Verlagsges. Geest u. Portig., 1970, 13th ed.
Yokoyama, F., Masada, I., Shimaura, K., Ikawa, T., and Monobe, K., Colloid Polym. Sci., 1986, vol. 264, p. 595.
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This work was supported by the Ministry of Science and Higher Education of the Russian Federation.
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Bakeeva, I.V., Doktorova, A.V., Damshkaln, L.G. et al. A Study of Cryostructuring of Polymer Systems. 54. Hybrid Organo-Inorganic Poly(vinyl alcohol) Cryogels Filled with In situ Formed Silica. Colloid J 83, 49–63 (2021). https://doi.org/10.1134/S1061933X21010026
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DOI: https://doi.org/10.1134/S1061933X21010026