Abstract
The regularities of the thermal relaxation of structural defects (paramagnetic centers and microdistortions), as well as the sizes of coherent-scattering regions and the external surface, of mechanically activated МоО3 have been studied with the use of X-ray diffraction, electron paramagnetic resonance, and adsorption/desorption methods. It has been revealed that heating of activated samples at temperatures below 450°C is accompanied by the death of paramagnetic centers, annealing of microdistortions, and liberation of molecular oxygen. It has been assumed that oxygen results from the rupture of deformed Mo–O–Mo bridge bonds formed by its atoms. Above 450°C, recrystallization processes occur, which are accompanied by an increase in the sizes of the coherent-scattering regions and the MoO3 (monoclinic) → MoO3 (orthorhombic) phase transition. The thermal stability of the external particle surface depends on mechanical activation conditions. For samples activated at early stages of activation (fracture regime), the specific surface area decreases by more than an order of magnitude, when a temperature of 450°C is reached. At higher activation doses (friction regime), the sample is not sintered in the same temperature range.
Similar content being viewed by others
References
Suryanarayana, C., Prog. Mater. Sci., 2001, vol. 46, p. 1.
Baláž P., Achimovicová M., Baláž M., Billik, P., Cherkezova-Zheleva, Z., Criado, J.M., Delogu, F., Dutková, E., Gaffet, E., Gotor, F.J., Kumar, R., Mitov, I., Rojac, T., Senna, M., Streletskii, A., and Wieczorek-Ciurowa, K., Chem. Soc. Rev., 2013, vol. 42, p. 7571.
Grigorieva, T.F., Barinova, A.P., and Lyakhov, N.Z., J. Nanopart. Res., 2003, vol. 5, p. 439.
Streletskii, A.N., Kolbanev, I.V., Borunova, A.B., and Butyagin, P.Yu., in Experimental and Theoretical Studies in Modern Mechanochemistry, Delogu, F. and Mulas, G., Eds., Kerala: Transworld Research Network, 2010, p. 192.
Fundamental’nye osnovy mekhanicheskoi aktivatsii, mekhanosinteza i mekhanokhimicheskikh tekhnologii (Fundamentals of Mechanical Activation, Mechanosynthesis and Mechanichemnical Technologies), Avvakumov, E.G., Ed., Novosibirsk Sib. Otd. RAN, 2010.
Mekhanokompozity—prekursory dlya sozdaniya materialov s novymi svoistvami (Mechanocomposites as Precursors for Creation of Materials with New Properties), Lomovskii, O.I., Ed, Novosibirsk Sib. Otd. RAN, 2010.
Dolgoborodov, A.Yu. and Streletskii, A.N., RF Patent 2235085, 2004.
Dreizin, E. and Schoenitz, M., US Patent 7524355 B2, 2009.
Dolgoborodov, A.Yu., Makhov, M.N., Streletskii, A.N., Kolbanev, A.N., Gogulya, M.F., and Fortov, V.E., Khim. Fiz., 2004, vol. 23, no. 9, p. 85.
Dolgoborodov, A.Yu., Streletskii, A.N., Makhov, M.N., Teselkin, V.A., Guseinov, Sh.L., Storozhenko, P.A., and Fortov, V.E., Khim. Fiz., 2012, vol. 31, no. 8, p. 37.
Dolgoborodov, A.Yu., Fiz. Goreniya Vzryva, 2015, vol. 51, p. 102.
Dreizin, E., Prog. Energy Combust. Sci., 2009, vol. 35, p. 141.
Williams, R.A., Schoenitz, M., Ermoline, A., and Dreizin, E., Thermochim. Acta, 2014, vol. 594, p. 1.
Ermoline, A., Schoenitz, M., and Dreizin, E.L., Combust. Flame, 2011, vol. 158, p. 1076.
Andryushkova, O.V., Poluboyarov, V.A., Pauli, I.A., and Korotaeva, Z.A., Mekhanokhimiya sozdaniya materialov s zadannymi svoistvami (Mechanochemistry of Production of Materials with Desired Properties), Novosibirsk NGTU, 2010.
Polubojarov, V.A., Kiselevich, S.N., Kirichenko, O.A., Pauli, I.A., Korotaeva, Z.A., Dektjarev, S.P., and Ancharov, A.I., Inorg. Mater., 1998, vol. 34, p. 1152.
Mestl, G., Herzog, B., Schlogl, R., and Knozinger, H., Langmuir, 1995, vol. 11, p. 3027.
Mestl, G., Verbruggen, N.F.D., Bosch, E., and Knozinger, H., Langmuir, 1996, vol. 12, p. 2961.
Sivak, M.V., Streletskii, A.N., Kolbanev, I.V., Leonov, A.V., and Permenov, D.G., Colloid J., 2015, vol. 77, p. 333.
Streletskii, A.N., Abstracts of Papers, 2nd Int. Conf. on Structural Applications of Mechanical Alloying, De Barbadillo, J.J., Froes, F.H., and Schwarz, R., Eds., 1993, p. 51.
O’Brien, M.G. and Jacques S.D.M., J. Phys. Chem., 2009, vol. 113, p. 4890.
Schoenitz, M., Umbrajkar, S., and Dreizin, E.L., J. Propulsion Power, 2007, vol. 23, p. 683.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.V. Sivak, A.N. Streletskii, I.V. Kolbanev, A.V. Leonov, E.N. Degtyarev, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 5, pp. 618–628.
Rights and permissions
About this article
Cite this article
Sivak, M.V., Streletskii, A.N., Kolbanev, I.V. et al. Thermal relaxation of defects in nanosized mechanically activated МоО3 . Colloid J 78, 674–684 (2016). https://doi.org/10.1134/S1061933X16050185
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X16050185