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Liquid immiscibility in the system NaF–H2O and microlite solubility at 800°C

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Abstract

The NaF effect on microlite solubility at 800°C and 170, 200, and 230 MPa is studied experimentally. The immiscibility boundaries and compositions of fluid phases L1 and L2 are defined in the system NaF–H2O at 800°C. It is established that microlite solubility increase in the L1 phase, as compared with a homogeneous solution, is explained by the appearance in the L1 phase of “free” HF in an amount of 0.025 ± 0.003 mol kg–1 H2O. The model of “acidification” L1 and “alkalizing” L2 is supposed.

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References

  1. Z. A. Kotelnikova and A. R. Kotelnikov, Geol. Ore Deposits 52 (2), 154–166 (2010).

    Article  Google Scholar 

  2. I. S. Peretyazhko, Petrology 17 (2), 178–201 (2009).

    Article  Google Scholar 

  3. J. J. Hemley, G. L. Cygan, and W. M. d’Angelo, Geology 14, 377–379 (1986).

    Article  Google Scholar 

  4. G. L. Cyagn, J. J. Hemley, and M. W. Doughten, in Proc. 9th V. E. McKelvey Forum on Mineral and Energy Resources (U.S. Geol. Surv., Washington, 1994), Circular 1103-A, pp. 26–27.

    Google Scholar 

  5. K. I. Shmulovich, S. I. Tkachenko, and N. V. Plyasunova, in Fluids in the Crust: Equilibrium and Transport Properties (Chapman and Hall, London, 1995), pp. 193–214.

    Book  Google Scholar 

  6. S. D. Malinin and N. A. Kurovskaya, Geochem. Int. 34 (1), 45–52 (1996).

    Google Scholar 

  7. Yu. V. Shvarov and E. N. Bastrakov, HCh: a Software Package for Geochemical Equilibrium Modelling. User’s Guide (Australian Geol. Suirv. Org., Canberra, 1999), Record No. 25.

    Google Scholar 

  8. Yu. V. Shvarov, Geochem. Int. 46 (8), 834–839 (2008).

    Article  Google Scholar 

  9. Yu. V. Shvarov, in Proc. 9th Int. Conf. “New Ideas in Earth Sciences” (Russ. State Geol. Prospect. Univ. Named after Sergo Ordzhonikidze, Moscow, 2009), p. 289.

    Google Scholar 

  10. H. C. Helgeson and D. H. Kirkham, Am. J. Sci. 274, 1089–1098 (1974).

    Article  Google Scholar 

  11. J. W. Johnson, E. H. Oelkers, and H. C. Helgeson, Comput. Geosci. 18, 899–947 (1992).

    Article  Google Scholar 

  12. R. P. Rafal’skii, Hydrothermal Equilibria and Mineral Formation (Atomizdat, Moscow, 1973) [in Russian].

    Google Scholar 

  13. H. C. Helgeson and D. H. Kirkham, Am. J. Sci. 274, 1199 (1974).

    Article  Google Scholar 

  14. G. P. Zaraiskii, A. M. Aksyuk, V. S. Korzhinskaya, N. P. Kotova, A. F. Redkin, and G. P. Borodulin, in Experimental Studies of Endogenic Processes (Institute of Experiment. Miner. Russ. Acad. Sci., Chernogolovka, 2008), pp. 86–109 [in Russian].

    Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Experimental Mineralogy, Russian Academy of Sciences, ul. Akad. Osip’yana 4, Chernogolovka, Moscow region, 142432, Russia

    A. F. Redkin, N. P. Kotova & Yu. B. Shapovalov

Authors
  1. A. F. Redkin
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  2. N. P. Kotova
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  3. Yu. B. Shapovalov
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Correspondence to A. F. Redkin.

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Published in Russian in Doklady Akademii Nauk, 2016, Vol. 469, No. 2, pp. 210–214.

The article was translated by the authors.

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Redkin, A.F., Kotova, N.P. & Shapovalov, Y.B. Liquid immiscibility in the system NaF–H2O and microlite solubility at 800°C. Dokl. Earth Sc. 469, 722–727 (2016). https://doi.org/10.1134/S1028334X16070151

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  • DOI: https://doi.org/10.1134/S1028334X16070151

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