Abstract
The possibility of forming hybrid coatings based on cobalt and nickel oxides immobilized in a chitosan polymer matrix on the surface of AISI 304 stainless steel using the non-steady-state electrolysis method is shown. The study of the morphology and surface structure of the coatings developed is carried out using scanning electron microscopy. According to X-ray spectral microanalysis, the main elements of the hybrid coatings are O, C, Co, and Ni. The formation of polyelectrolyte complexes and the immobilization of metal oxides in a chitosan polymer matrix are proven by infrared (IR) spectroscopy. Studying the phase composition of the hybrid coatings developed is carried out using X-ray diffraction and transmission-electron-microscopy methods. Identification of the X-ray diffraction patterns is difficult because of the amorphous structure and high dispersion of the coating substance. Therefore, the structure and most probable main phases of the hybrid coatings developed are established using transmission electron microscopy. It is established that oxide compounds of the coating represent particle agglomerates. It is shown that the results of structural investigation of hybrid coatings obtained using different physical-chemical methods are correlated and complementary.
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Khramenkova, A.V., Ariskina, D.N., Moshchenko, V.V. et al. Study of the Structure of Hybrid Coatings on the Surface of Stainless Steel Obtained Using an Alternating Asymmetric Current. J. Surf. Investig. 16, 682–686 (2022). https://doi.org/10.1134/S102745102205007X
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DOI: https://doi.org/10.1134/S102745102205007X