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Composite electrodes for proton conducting electrolyte of CaZr0.95Sc0.05O3 – δ

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Abstract

A new method of obtaining gastight ceramic based on CaZr0.95Sc0.05O3 – δ is presented. The microstructure and electric properties of the obtained samples, same as the behavior of composite electrodes in contact with this electrolyte, are studied for application of the obtained results in the technology of formation of electrochemical devices. The design of bilayer electrodes is suggested, in which the materials tested as the functional layer were layered lanthanum nickelate La2NiO4 + δ and substituted lanthanum nickelate La1.7Ca(Sr,Ba)0.3NiO4 + δ in combination with the electrolyte components of Ce0.8Sm0.2O2 – δ and BaCe0.89Gd0.1Cu0.01O3 – δ. The collector layer used was lanthanum nickelate–ferrite LaNi0.6Fe0.4O3 – δ and manganite La0.6Sr0.4MnO3 – δ that are characterized by high electron conductivity, low layer resistance and are close by their values of coefficient of linear thermal expansion to the materials of functional layers. Electrochemical activity of the obtained electrodes are compared with the characteristics of composite electrodes based on lanthanum ferrite–cobaltite La0.6Sr0.4Fe0.8Co0.2O3 – δ and deficient lanthanum manganite La0.75Sr0.2MnO3 – δ.

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References

  1. Kalyakin, A., Fadeev, G., Demin, A., Gorbova, E., Brouzgou, A., Volkov, A., and Tsiakaras, P., Electrochim. Acta, 2014, vol. 141, p. 120.

    Article  CAS  Google Scholar 

  2. Gorelov, V.P., Balakireva, V.B., Kuz’min, A.V., and Plaksin, S.V., Inorg. Mater., 2014, vol. 50, p. 495.

    Article  CAS  Google Scholar 

  3. Gorelov, V. P., Balakireva, V.B., and Kuz’min, A.V., Phys. Solid State, 2016, vol. 58, p. 14.

    Article  Google Scholar 

  4. Davies, R.A., Islam, M.S., and Gale, J.D., Solid State Ionics, 1999, vol. 126, p. 323.

    Article  CAS  Google Scholar 

  5. Tsidilkovski, V.I., Solid State Ionics, 2003, vols. 162–163, p. 47.

    Google Scholar 

  6. Matsumoto, H., Hayashi, H., Shimura, T., Iwahara, H., and Yogo, T., Solid State Ionics, 2003, vol. 161, p. 93.

    Article  CAS  Google Scholar 

  7. Tolchard, J. and Grande, T., J. Solid State Chem., 2007, vol. 180, p. 2808.

    Article  CAS  Google Scholar 

  8. Dailly, J., Fourcade, S., Largeteau, A., Mauvy, F., Grenier, J.C., and Marrony, M., Electrochim. Acta, 2010, vol. 55, p. 5847.

    Article  CAS  Google Scholar 

  9. Hou, J., Zhu, Zh., Qian, J., and Liu, W., J. Power Sources, 2014, vol. 264, p. 67.

    Article  CAS  Google Scholar 

  10. Upasen, S., Batocchi, P., Mauvy, F., Slodczyk, A., and Colomban, Ph., J. Alloys Compd., 2015, vol. 622, p. 1074.

    Article  CAS  Google Scholar 

  11. Boehm, E., Bassat, J.-M., Dordor, P., Mauvy, F., Grenier, J.C., and Stevens, Ph., Solid State Ionics, 2005, vol. 176, p. 2717.

    Article  CAS  Google Scholar 

  12. Tang, J.P., Dass, R.I., and Manthiram, A., Mater. Res. Bull., 2000, vol. 35, p. 411.

    Article  CAS  Google Scholar 

  13. Pikalova, E.Yu., Bogdanovich, N.M., Kolchugin, A.A., Osinkin, D.A., and Bronin, D.I., Procedia Eng., 2014, vol. 98, p. 105.

    Article  CAS  Google Scholar 

  14. Pikalova, E.Yu., Bogdanovich, N.M., Kolchugin, A.A., Brouzgou, A., Bronin, D.I., Plaksin, S.V., Khasanov, A.F., and Tsiakaras, P., ECS Trans., 2015, vol. 68, p. 809.

    Article  CAS  Google Scholar 

  15. Shen, Y., Zhao, H., Liu, X., and Xu, N., Phys. Chem. Chem. Phys., 2010, vol. 12, p. 15124.

    Article  CAS  Google Scholar 

  16. Bogdanovich, N.M., Bronin, D.I., Vdovin, G.K., Yaroslavtsev, I.Yu., and Kuzin, B.L, Russ. J. Electrochem., 2009, vol. 45, p. 456.

    Article  CAS  Google Scholar 

  17. Kuzin, B.L., Bogdanovich, N.M., Bronin, D.I., Yaroslavtsev, I.Yu., Vdovin, G.K., Kotov, Yu.A., Bagazeev, A.V., Medvedev, A.I., Murzakaev, A.M., Timoshenkova, O.P., and Stol’ts, A.K., Russ. J. Electrochem., 2007, vol. 43, p. 920.

    Article  CAS  Google Scholar 

  18. Neuimin, A.D., Fedin, V.V., Zhuravlev, B.V., Kozhevnikova, B.V., Bogdanovich, N.M., Khomyakova, N.G., and Maizner, E.A., RF Patent no. 1825575 (2003).

  19. Zhao, F., Jin, C., Yang, C., Wan, S., and Chen, F., J. Power Sources, 2011, vol. 196, p. 688.

    Article  CAS  Google Scholar 

  20. Bogdanovich, N.M., Gorelov, V.P., Balakireva, V.B., and Dem’yanenko, T.A., Russ. J. Electrochem., 2005, vol. 41, p. 576.

    Article  CAS  Google Scholar 

  21. Yaroslavtsev, I.Yu., Kuzin, B.L., Bronin, D.I., Vdovin, G.K., and Bogdanovich, N.M., Russ. J. Elecrochem., 2009, vol. 45, p. 875.

    Article  CAS  Google Scholar 

  22. Bogdanovich, N.M., Kuzin, B.L., Bronin, D.I., Dem’yanenko, T.A., Yaroslavtsev, I.Yu., Kotov, Yu.A., Murzakaev, A.M., and Bagazeev, A.V., RF Patent no. 2322730 (2008).

  23. Li, S., Yan, R., Wu, G., Xie, K., and Cheng, J., Int. J. Hydrogen Energy, 2013, vol. 38, p. 14943.

    Article  CAS  Google Scholar 

  24. Yajima, T., Kazeoka, H., Yogo, T., and Iwahara, H., Solid State Ionics, 1991, vol. 47, p. 271.

    Article  CAS  Google Scholar 

  25. Kolchugin, A., Pikalova, E.Yu., Bogdanovich, N.M., Bronin, D.I., Pikalov, S.M., Plaksin, S.V., Ananyev, M.V., and Eremin, V.A., Solid State Ionics, 2016, vol. 288, p. 48.

    Article  CAS  Google Scholar 

  26. Kolchugin, A.A., Pikalova, E.Yu., Bogdanovich, N.M., and Bronin, D.I., Russ. J. Electrochem., 2015, vol. 51, p. 483.

    Article  CAS  Google Scholar 

  27. Ling, Y., Yu, J., Iin, B., Zhang, X., Zhao, L., and Liu, X., J. Power Sources, 2011, vol. 196, p. 2631.

    Article  CAS  Google Scholar 

  28. Chen, Y., Gu, Q., Tian, D., Ding, Y., Lu, X., Yu, W., Isimjan, T.T., and Lin, B., Int. J. Hydrogen Energy, 2014, vol. 39, p. 13665.

    Article  CAS  Google Scholar 

  29. Hou, J., Zho, Zh., Qian, J., and Liu, W., J. Power Sources, 2014, vol. 264, p. 67.

    Article  CAS  Google Scholar 

  30. Poetzsch, D., Merkle, R., and Maier, J., J. Electrochem. Soc., 2015, vol. 162, p. F939.

  31. Lyagaeva, J., Medvedev, D., Pikalova, E., Plaksin, S., Brouzgou, A., Demin, A., and Tsiakaras, P., Int. J. Hydrogen Energy, 2016, vol. 41. doi 10.1016/j.ijhydene.2016.07.248

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    E. Yu. Pikalova, N. M. Bogdanovich & A. V. Kuz’min

  2. Ural Federal University, Yekaterinburg, 620002, Russia

    E. Yu. Pikalova & A. V. Kuz’min

Authors
  1. E. Yu. Pikalova
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  2. N. M. Bogdanovich
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  3. A. V. Kuz’min
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Correspondence to E. Yu. Pikalova.

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Original Russian Text © E.Yu. Pikalova, N.M. Bogdanovich, A.V. Kuz’min, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 7, pp. 846–855.

Published on the basis of a report delivered at the 13th International Meeting “Fundamental Problems of Solid State Ionics,” Chernogolovka, 2016.

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Pikalova, E.Y., Bogdanovich, N.M. & Kuz’min, A.V. Composite electrodes for proton conducting electrolyte of CaZr0.95Sc0.05O3 – δ . Russ J Electrochem 53, 752–760 (2017). https://doi.org/10.1134/S1023193517070096

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  • DOI: https://doi.org/10.1134/S1023193517070096

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